Bronsted acid-catalyzed hydroarylation of activated olefins

被引：16
|
作者：
Fleischer, Ivana [1 ,2 ]
Pospech, Jola [2 ]
机构：
[1] Univ Regensburg, Inst Organ Chem, D-93040 Regensburg, Germany
[2] Univ Rostock, Leibniz Inst Katalyse eV, D-18059 Rostock, Germany
来源：
RSC ADVANCES | 2015年 / 5卷 / 01期
关键词：
O-QUINONE METHIDES; C-H ACTIVATION; INTERMOLECULAR HYDROARYLATION; UNACTIVATED OLEFINS; BENZYLIC ALCOHOLS; IN-SITU; STYRENES; ALKYLATION; INDOLES; ARENES;
D O I：
10.1039/c4ra13647k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A mild, regiospecific Bronsted acid-catalyzed hydroarylation of activated olefins, capable of the formation of quinone methide-like intermediates, has been investigated. Variously substituted 2- and 4-vinylphenols, 4-vinylaniline or 6-vinyl-naphthalen-2-ol were successfully implemented in a sequential protonation and Friedel-Crafts-type alkylation reaction of electron-rich arenes.
引用
收藏
页码：493 / 496
页数：4
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