Synthesis and X-ray characterization of a monomeric Cp-free d1-imido-vanadium(IV) complex

被引:38
作者
Lorber, C [1 ]
Donnadieu, B [1 ]
Choukroun, R [1 ]
机构
[1] CNR, Equipe Precurseurs Mol & Mat, Chim Coordinat Lab, UPR 8241, F-31077 Toulouse 04, France
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2000年 / 24期
关键词
D O I
10.1039/b008761k
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Straightforward synthesis of the new imido complexes ArN=V(NMe2)(2)(HNMe2)(2) 1 and ArN=VCl2(HNMe2)(2) 2 (Ar=2,6-i-Pr2C6H3) is described along with the molecular structure of 2 and preliminary ethylene polymerization catalytic studies.
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页码:4497 / 4498
页数:2
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