Investigation of Ce3+ luminescence in borate-rich borosilicate glasses

被引：13

作者：

Kielty, M. W. ^{[1
]}

Dettmann, M. ^{[2
]}

Herrig, V. ^{[2
]}

Chapman, M. G. ^{[1
]}

Marchewka, M. R. ^{[1
]}

Trofimov, A. A. ^{[1
]}

Akgun, U. ^{[2
]}

Jacobsohn, L. G. ^{[1
,3
]}

机构：

[1] Clemson Univ, Dept Mat Sci & Engn, Clemson, SC 29634 USA

[2] Coe Coll, Dept Phys, Cedar Rapids, IA 52402 USA

[3] Clemson Univ, COMSET Ctr Opt Mat Sci & Engn Technol, Anderson, SC 29625 USA

来源：

JOURNAL OF NON-CRYSTALLINE SOLIDS | 2017年 / 471卷

基金：

美国国家科学基金会;

关键词：

Borosilicate glass; Cerium; Raman; Luminescence; Defects; VIBRATIONAL-SPECTRA; RAMAN-SCATTERING; SILICA; BORON; CERIUM(III); DEPENDENCE; DENSITY;

D O I：

10.1016/j.jnoncrysol.2017.06.022

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

An investigation of Ce-activated borate-rich borosilicate glasses was performed in a composition range previously unexplored, with high B2O3:SiO2 ratios from 4.83:1 to 8.75:1. Glass samples were prepared by the melt quenching method in air. Samples were individually heated for 15 min at 1000 degrees C, evaluated for weight loss due to the release of volatile species, followed by a final melt for 15 min at 1000 degrees C, and then annealed at 350 degrees C for one hour to enhance stability. Particular emphasis was placed on the luminescence of the glasses investigated under X-ray and ultraviolet excitation. Luminescence was interpreted in terms of defects and Ce3+ in different environments. The results indicated it was possible to achieve a composition of the host matrix that exhibited ultraviolet transparency cutoff at 326 nm and a well-defined emission from Ce3+, especially under X-ray excitation.

引用

页码：357 / 361

页数：5

共 49 条

[41] Optically active oxygen-deficiency-related centers in amorphous silicon dioxide [J].

Skuja, L .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 1998, 239 (1-3) :16-48

[42] Thermally stimulated luminescence of X-ray irradiated sodium borate glasses doped with cerium(III) and samarium(III) [J].

Tanaka, K ;

Hirao, K ;

Tanaka, H ;

Soga, N .

JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1996, 35 (4A) :2170-2175

[43] Inorganic thermal-neutron scintillators [J].

van Eijk, CWE ;

Bessière, A ;

Dorenbos, P .

NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT, 2004, 529 (1-3) :260-267

[44] RAMAN INVESTIGATION OF VITREOUS AND MOLTEN BORIC OXIDE [J].

WALRAFEN, GE ;

SAMANTA, SR ;

KRISHNAN, PN .

JOURNAL OF CHEMICAL PHYSICS, 1980, 72 (01) :113-120

[45] VIBRATIONAL-SPECTRA OF OXYGEN-ISOTOPICALLY AND BORON-ISOTOPICALLY SUBSTITUTED B2O3 GLASSES [J].

WINDISCH, CF ;

RISEN, WM .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 1982, 48 (2-3) :307-323

[46] Exploratory Research on the Development of Novel Ce3+-Activated Phosphate Glass Scintillators [J].

Wisniewski, Dariusz ;

Boatner, Lynn A. ;

Ramey, Joanne O. ;

Wisniewska, Monika ;

Neal, John S. ;

Jellison, Gerald E. .

IEEE TRANSACTIONS ON NUCLEAR SCIENCE, 2008, 55 (06) :3692-3702

[47] Spectroscopic properties of Ce3+ doped silica annealed at different temperatures [J].

Xu, G. Q. ;

Zheng, Z. X. ;

Tang, W. M. ;

Wu, Y. C. .

JOURNAL OF LUMINESCENCE, 2007, 124 (01) :151-156

[48]

Zadneprovski BI, 2005, FUNCT MATER, V12, P261

[49]

ZHOU WC, 1995, J NON-CRYST SOLIDS, V184, P84

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