Diethylenetriammonium aquapentachloroferrate(III) chloride: Structure and magnetic properties

被引：6

作者：

James, Bruce D. ^{[1
]}

Mrozinski, Jerzy

Klak, Julia

Skelton, Brian W.

White, Allan H.

机构：

[1] La Trobe Univ, Dept Chem, Bundoora, Vic 3086, Australia

[2] Univ Wroclaw, Dept Chem, PL-50383 Wroclaw, Poland

[3] Univ Western Australia, Sch Biomed Biomol & Chem Sci, Crawley, WA 6009, Australia

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2007年 / 633卷 / 07期

关键词：

iron; aquapentachloroferrate(III); diethylenetriammonium salt; crystal structure; magnetic properties;

D O I：

10.1002/zaac.200700019

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Diethylenetriamine (dien) and iron(III) chloride in aqueous HCl yield (dienH(3)) [FeCl5(H2O)]Cl, in which the chloroferrate(III) anion is significantly distorted from octahedral symmetry due to the extensively hydrogen-bonded lattice. On cooling, the high spin Fe-III material shows weak antiferromagnetic coupling that results in a Neel temperature of 2.70 K.

引用

页码：974 / 978

页数：5

共 24 条

[1] CRYSTAL AND MOLECULAR-STRUCTURES OF RINNEITE, SODIUM TRIPOTASSIUM HEXACHLOROFERRATE(II), AND HEXAAMMINECOBALT(III) HEXACHLOROFERRATE(III) - COMPARISON OF IRON CHLORIDE DISTANCES IN HEXACHLOROFERRATES(II) AND HEXACHLOROFERRATES(III) [J].

BEATTIE, JK ;

MOORE, CJ .

INORGANIC CHEMISTRY, 1982, 21 (04) :1292-1295

[2]

Carlin R. L, 1986, MAGNETOCHEMISTRY

[3]

CLAUSEN CA, 1968, INORG CHEM, V8, P2662

[4]

CREASER CS, 1979, J INORG NUCL CHEM, V41, P469

[5]

Feist M, 1999, Z ANORG ALLG CHEM, V625, P141, DOI 10.1002/(SICI)1521-3749(199901)625:1<141::AID-ZAAC141>3.0.CO

[6]

2-W

[7] CRYSTAL-STRUCTURE OF DIAMMONIUM AQUAPENTACHLOROFERRATE(III) [J].

FIGGIS, BN ;

RASTON, CL ;

SHARMA, RP ;

WHITE, AH .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1978, 31 (12) :2717-2720

[8] Alkylammonium hexachlorometallates .1. Crystallization properties and crystal structure of diethylenetriammonium hexachlororhodate, [H3N(CH2)(2)NH2(CH2)(2)NH3][RhCl6] [J].

Frank, W ;

Reiss, GJ ;

Kleinwachter, I .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1996, 622 (04) :729-733

[9] The hexachloroferrate(III) anion stabilized in hydrogen bonded packing arrangements. A comparison of the X-ray crystal structures and low temperature magnetism of tetrakis(methylammonium)hexachloroferrate(III)chloride(I) and tetrakis(hexamethylenediammonium)hexachloroferrate(III)tetrachloroferrate(III)tetrachloride(II) [J].

James, BD ;

Bakalova, M ;

Liesegang, J ;

Reiff, WM ;

Hockless, DCR ;

Skelton, BW ;

White, AH .

INORGANICA CHIMICA ACTA, 1996, 247 (02) :169-174

[10] THE UNSOLVATED PENTACHLOROFERRATE(III) ION - X-RAY CRYSTAL-STRUCTURE AND LOW-TEMPERATURE MAGNETISM OF TETRAMETHYLPIPERAZINIUM PENTACHLOROFERRATE(III) [J].

JAMES, BD ;

LIESEGANG, J ;

BAKALOVA, M ;

REIFF, WM ;

SKELTON, BW ;

WHITE, AH .

INORGANIC CHEMISTRY, 1995, 34 (08) :2054-2057

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