Catalytic Phosphorylation of Aromatic C-H Bonds: from Traditional Approaches to Electrochemistry

被引：7

作者：

Strekalova, Sofia ^{[1
]}

Khrizanforov, Mikhail ^{[1
]}

Sinyashin, Oleg ^{[1
]}

Budnikova, Yulia ^{[1
]}

机构：

[1] RAS, FRC Kazan Sci Ctr, Arbuzov Inst Organ & Phys Chem, 8 Arbuzov Str, Kazan 420088, Russia

来源：

CURRENT ORGANIC CHEMISTRY | 2019年 / 23卷 / 16期

关键词：

Phosphorylation; C-H activation; catalysis; electrochemical synthesis; heteroaromatic compounds; organophosphorus compounds;

D O I：

10.2174/1385272822666191007145336

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The interest in organophosphorus compounds with a C-P bond is due to their wide use in various fields, especially in medicine and agrochemistry. Prominent examples of anti-cancer, antibacterial, and anti-HIV agents are therapeutic candidates containing a phosphonic acid group fragment. This review provides modern synthetic methods for obtaining phosphorylated aromatic and heteroaromatic compounds with the participation of complexes and salts of various metals developed in recent years as well modern protocol - electrochemical synthesis which allows carrying out reactions at room temperature and normal pressure with no additional oxidants or bases. Herein, we demonstrate new trends and evolution of phosphorylation reactions in catalysis.

引用

页码：1756 / 1770

页数：15

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