Ground- and Excited-State Quinones: Perspectives in Organocatalysis and Visible-Light Photocatalysis

被引:35
|
作者
Lerch, Stephanie [1 ]
Unkel, Lisa-Natascha [1 ]
Wienefeld, Patrick [1 ]
Brasholz, Malte [1 ]
机构
[1] Univ Hamburg, Dept Chem, Inst Organ Chem, D-20146 Hamburg, Germany
关键词
quinones; organocatalysis; photochemistry; photooxidations; tandem reactions; AEROBIC OXIDATION; ELECTRON-TRANSFER; SINGLET OXYGEN; QUANTUM YIELDS; C-H; ANTHRAQUINONE; DDQ; AMINES; BOND; DEPROTECTION;
D O I
10.1055/s-0034-1379363
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Quinone organocatalysis is an emerging area, and this report highlights some recently developed thermal and photocatalytic reactions, with particular emphasis on photooxygenation reactions. Further, it is discussed how the orthogonal ground- and excited-state reactivities of quinones can be utilized for the development of tandem catalytic processes.
引用
收藏
页码:2673 / 2680
页数:8
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