A three-dimensional honeycomb-like network constructed with novel "sinusoidal" one-dimensional chains via hydrogen bonding and π-π interactions

被引：73

作者：

Ghoshal, D

Maji, TK

Mostafa, G

Lu, TH ^{[1
]}

Chaudhuri, NR

机构：

[1] Natl Tsing Hua Univ, Dept Phys, Hsinchu 300, Taiwan

[2] Indian Assoc Cultivat Sci, Dept Inorgan Chem, Kolkata 700032, W Bengal, India

来源：

CRYSTAL GROWTH & DESIGN | 2003年 / 3卷 / 01期

关键词：

D O I：

10.1021/cg025574p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A one pot reaction of MnCl2, acetylene dicarboxylate (C4O42-), and 1,2-bis(4-pyridyl)ethane (bpe) leads to a compound formulated as [{Mn(bpe)(H2O)(4)}C4O4)-4.5H(2)O] and has been shown by single crystal structure analysis to be a three-dimensional network with hexagonal and rhombohedral channels encapsulating C(4)O(4)2- and water molecules, constructed by the one-dimensional "sinusoidal" [Mn(bpe)(H2O)(4)](n)(2+) cationic chains through extensive hydrogen-bonding and pi-pi interactions.

引用

页码：9 / 11

页数：3

共 29 条

[1] New examples of self-catenation in two three-dimensional polymeric co-ordination networks [J].