Mechanical properties and flame-retardant of PP/MRP/Mg(OH)2/Al(OH)3 composites

被引:50
作者
Liang, J. Z. [1 ]
Feng, J. Q. [1 ]
Tsui, C. P. [2 ]
Tang, C. Y. [2 ]
Liu, D. F. [1 ]
Zhang, S. D. [1 ]
Huang, W. F. [2 ]
机构
[1] S China Univ Technol, Sch Mech & Automot Engn, Res Div Green Funct Mat & Equipment, Guangzhou 510640, Guangdong, Peoples R China
[2] Hong Kong Polytech Univ, Dept Ind & Syst Engn, Hong Kong, Hong Kong, Peoples R China
关键词
Polymer-matrix composites (PMCs); Thermal properties; Mechanical properties; Strength; Thermal analysis; MAGNESIUM-HYDROXIDE; PP COMPOSITES; POLYPROPYLENE; BEHAVIOR;
D O I
10.1016/j.compositesb.2014.10.054
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The flame retardant and mechanical properties of polypropylene (PP) composites filled with microencapsulated red phosphorus (MRP) and magnesium hydrate (Mg(OH)(2))/aluminum hydrate (Al(OH)(3)) were measured. It was found that the synergistic effects between the MRP and Mg(OH)(2)/Al(OH)(3) on the flame retardant and tensile properties of the composites were significant. The limit oxygen index and smoke density rank of the composites increased nonlinearly while the horizontal combustibility rate decreased nonlinearly with increasing the MRP weight fraction. The Young modulus and the tensile elongation at break increased while the tensile yield strength and tensile fracture strength decreased slightly with increasing the MRP weight fraction. Both the V-notched Izod and Charpy impact strength increased with increasing the MRP weight fraction. Moreover, the tensile yield strength of the composites estimated using an equation published previously was roughly close to the measured data. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:74 / 81
页数:8
相关论文
共 19 条
[1]   Dynamic flame retardancy of polypropylene filled with ammonium polyphosphate, pentaerythritol and melamine additives [J].
Chiu, SH ;
Wang, WK .
POLYMER, 1998, 39 (10) :1951-1955
[2]   Mechanical properties, fire performance and thermal stability of magnesium hydroxide sulfate hydrate whiskers flame retardant silicone rubber [J].
Fang, Shoulin ;
Hu, Yuan ;
Song, Lei ;
Zhan, Jing ;
He, Qingliang .
JOURNAL OF MATERIALS SCIENCE, 2008, 43 (03) :1057-1062
[3]   Tensile properties and stress whitening of polypropylene/polyolefin elastomer/magnesium hydroxide flame retardant composites for cable insulating application [J].
Hong, CH ;
Lee, YB ;
Bae, JW ;
Jho, JY ;
Nam, BU ;
Chang, DH ;
Yoon, SH ;
Lee, KJ .
JOURNAL OF APPLIED POLYMER SCIENCE, 2005, 97 (06) :2311-2318
[4]   Effect of flame retardants on flame retardant, mechanical, and thermal properties of sisal fiber/polypropylene composites [J].
Jeencham, Rachasit ;
Suppakarn, Nitinat ;
Jarukumjorn, Kasama .
COMPOSITES PART B-ENGINEERING, 2014, 56 :249-253
[5]   Preparation of Microencapsulated Red Phosphorus and Its Flame-Retardant Application in PP Composites [J].
Jiang Wen-jun ;
Li Zhe-zhao ;
Zhang Chun-xiang ;
Fang Jin ;
Yang Xu-jie ;
Lu Lu-de ;
Pu Long-juan .
SPECTROSCOPY AND SPECTRAL ANALYSIS, 2010, 30 (05) :1329-1335
[6]   Flame Retardant Synergism of Hydroxy Silicone Oil and Al(OH)3 in EVA Composites [J].
Jiao, C. M. ;
Chen, X. L. .
POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, 2009, 48 (06) :665-670
[7]   Flame-Retardant Properties of PP/Al(OH)3/Mg(OH)2/POE/ZB Nanocomposites [J].
Liang, J. Z. ;
Chen, Y. ;
Jiang, X. H. .
POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, 2012, 51 (05) :439-445
[8]   Reinforcement and quantitative description of inorganic particulate-filled polymer composites [J].
Liang, Ji-Zhao .
COMPOSITES PART B-ENGINEERING, 2013, 51 :224-232
[9]   A study of the flame-retardant properties of polypropylene/Al(OH)3/Mg(OH)2 composites [J].
Liang, Jizhao ;
Zhang, Yingjie .
POLYMER INTERNATIONAL, 2010, 59 (04) :539-542
[10]   Mechanical properties and morphology of glass bead-filled polypropylene composites [J].
Liang, JZ ;
Li, RKY .
POLYMER COMPOSITES, 1998, 19 (06) :698-703