Facile Synthesis of Porous Dendritic Bimetallic Platinum-Nickel Nanocrystals as Efficient Catalysts for the Oxygen Reduction Reaction

被引：49
作者：
Eid, Kamel [1 ,2 ,3 ]
Wang, Hongjing [1 ]
Malgras, Victor [4 ]
Alothman, Zeid Abdullah [5 ]
Yamauchi, Yusuke [4 ,5 ]
Wang, Liang [1 ]
机构：
[1] Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310014, Zhejiang, Peoples R China
[2] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Jilin, Peoples R China
[3] Univ Chinese Acad Sci, Beijing 100039, Peoples R China
[4] Natl Inst Mat Sci NIMS, World Premier Int WPI, Res Ctr Mat Nanoarchitecton MANA, 1-1 Namiki, Tsukuba, Ibaraki 3050044, Japan
[5] King Saud Univ, Coll Sci, Dept Chem, Riyadh 11451, Saudi Arabia
来源：
CHEMISTRY-AN ASIAN JOURNAL | 2016年 / 11卷 / 09期
基金：
中国国家自然科学基金;
关键词：
alloys; dendritic structures; electrochemistry; nanoparticles; reduction; ONE-STEP SYNTHESIS; PT-NI; ELECTROCATALYTIC ACTIVITY; HOLLOW NANOPARTICLES; REACTION PERFORMANCE; CARBON; SURFACE; NANOSTRUCTURES; STABILITY; OCTAHEDRA;
D O I：
10.1002/asia.201600055
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Certain bimetallic nanocrystals (NCs) possess promising catalytic properties for electrochemical energy conversion. Herein, we report a facile method for the one-step synthesis of porous dendritic PtNi NCs in aqueous solution at room temperature that contrasts with the traditional multistep thermal decomposition approach. The dendritic PtNi NCs assembled by interconnected arms are efficient catalysts for the oxygen reduction reaction. This direct and efficient method is favorable for the up-scaled synthesis of active catalysts used in electrochemical applications.
引用
收藏
页码：1388 / 1393
页数：6
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