Ion-radical salts: a new type of molecular ferrimagnet

被引：8

作者：

Turner, SS

Day, P

机构：

[1] Univ Exeter, Dept Chem, Exeter EX4 4QD, Devon, England

[2] UCL Royal Inst Great Britain, Davy Faraday Res Lab, London W1S 4BS, England

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2005年 / 15卷 / 01期

关键词：

D O I：

10.1039/b412696n

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Long-range ferrimagnetic order in which one magnetic sub-lattice is formed from partly-occupied p-orbitals and the other from d-orbitals can be achieved in molecular ion-radical salts where the cations are oxidised organo-chalcogen donors and the anions are 3d-metal complexes containing both N-bonded NCS and planar N-heterocyclic ligands. Overlaps between p-orbitals of the radical cations and those of the heterocycle are implicated in the cation-anion exchange pathway.

引用

页码：23 / 25

页数：3

共 24 条

[1]

BRAUER G, 1975, HDB PRAPARATIVEN ANO, V3, P1516

[2]

Christensen O. T., 1892, J PRAKT CHEM, V45, P213

[3]

CHRISTENSEN OT, 1892, J PRAKT CHEM, V45, P356

[4]

DAY P, 2003, ISIS ANN REPORT SCI, P8

[5]

GOMEZGARCIA CJ, IN PRESS

[6]

Goodenough J. B., 1963, MAGNETISM CHEM BOND

[7]

Ishiguro T., 1998, Organic Superconductors

[8] SUPERCONDUCTIVITY IN A SYNTHETIC ORGANIC CONDUCTOR (TMTSF)2PF6 [J].

JEROME, D ;

MAZAUD, A ;

RIBAULT, M ;

BECHGAARD, K .

JOURNAL DE PHYSIQUE LETTRES, 1980, 41 (04) :L95-L98

[9] Quasi-one-dimensional bis(ethylenedithio)tetrathiafulvalene charge-transfer salts with paramagnetic group 6 anions [J].

Kepert, CJ ;

Kurmoo, M ;

Truter, MR ;

Day, P .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (04) :607-613

[10] TTF based molecular magnets:: Structural and physical properties of new salts involving the [Cr(NCS)4(phen)]- anion [J].

Le Pevelen, D ;

Turner, SS ;

Day, P ;

Prout, K .

SYNTHETIC METALS, 2001, 121 (1-3) :1842-1843

← 1 2 3 →