Electromechanical properties of Nd-doped Bi4Ti3O12 films:: A candidate for lead-free thin-film piezoelectrics

被引:162
作者
Maiwa, H
Iizawa, N
Togawa, D
Hayashi, T
Sakamoto, W
Yamada, M
Hirano, S
机构
[1] Shonan Inst Technol, Dept Mat Sci & Engn, Kanagawa 2518511, Japan
[2] Nagoya Univ, Ctr Integrated Res Sci & Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan
[3] Nagoya Univ, Grad Sch Engn, Dept Appl Chem, Chikusa Ku, Nagoya, Aichi 4648603, Japan
关键词
D O I
10.1063/1.1560864
中图分类号
O59 [应用物理学];
学科分类号
摘要
Neodymium-doped Bi4Ti3O12 (BNT) films are evaluated for use as lead-free thin-film piezoelectrics in microelectromechanical systems. Bi4Ti3O12, Bi3.25La0.75Ti3O12, and Bi3.25Nd0.75Ti3O12 films were fabricated by chemical solution deposition on Pt/TiOx/SiO2/Si substrates. Nd substitution promoted random orientation with low (00l) diffraction peaks. The 1-mum-thick Bi3.25Nd0.75Ti3O12 film annealed at 750 degreesC exhibited a remanent polarization of 26 muC/cm(2). Typical butterfly field-induced strain loops were obtained in the BNT film capacitors. The electrically induced strain is 8.4x10(-4) under the bipolar driving field of 220 kV/cm. These results show that BNT is a promising candidate for use in lead-free thin-film piezoelectrics. (C) 2003 American Institute of Physics.
引用
收藏
页码:1760 / 1762
页数:3
相关论文
共 16 条
  • [1] Spatial variation of ferroelectric properties in Pb(Zr0.3, Ti0.7)O3 thin films studied by atomic force microscopy
    Christman, JA
    Kim, SH
    Maiwa, H
    Maria, JP
    Rodriguez, BJ
    Kingon, AI
    Nemanich, RJ
    [J]. JOURNAL OF APPLIED PHYSICS, 2000, 87 (11) : 8031 - 8034
  • [2] CRYSTAL SYMMETRY OPTICAL PROPERTIES AND FERROELECTRIC POLARIZATION OF BI4TI3O12 SINGLE CRYSTALS
    CUMMINS, SE
    CROSS, LE
    [J]. APPLIED PHYSICS LETTERS, 1967, 10 (01) : 14 - &
  • [3] Properties of aluminum nitride thin films for piezoelectric transducers and microwave filter applications
    Dubois, MA
    Muralt, P
    [J]. APPLIED PHYSICS LETTERS, 1999, 74 (20) : 3032 - 3034
  • [4] Preparation and properties of Bi4-xLaxTi3O12 ferroelectric thin films using excimer UV irradiation
    Hayashi, T
    Togawa, D
    Yamada, M
    Sakamoto, W
    Hirano, S
    [J]. JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 2002, 41 (11B): : 6814 - 6819
  • [5] HAYASHI T, IN PRESS JPN J APPL
  • [6] Platinum-assisted phase transition in bismuth-based layer-structured ferroelectric CaBi4Ti4O15 thin films
    Kato, K
    Suzuki, K
    Fu, DS
    Nishizawa, K
    Miki, T
    [J]. APPLIED PHYSICS LETTERS, 2002, 81 (17) : 3227 - 3229
  • [7] Electromechanical properties of SrBi2Ta2O9 thin films
    Kholkin, AL
    Brooks, KG
    Setter, N
    [J]. APPLIED PHYSICS LETTERS, 1997, 71 (14) : 2044 - 2046
  • [8] Interferometric measurements of electric field-induced displacements in piezoelectric thin films
    Kholkin, AL
    Wutchrich, C
    Taylor, DV
    Setter, N
    [J]. REVIEW OF SCIENTIFIC INSTRUMENTS, 1996, 67 (05) : 1935 - 1941
  • [9] Large remanent polarization of (Bi,Nd)4Ti3O12 epitaxial thin films grown by metalorganic chemical vapor deposition
    Kojima, T
    Sakai, T
    Watanabe, T
    Funakubo, H
    Saito, K
    Osada, M
    [J]. APPLIED PHYSICS LETTERS, 2002, 80 (15) : 2746 - 2748
  • [10] MAEDER MD, 2002, PIEZOELECTRIC MAT DE, P389