Simple analysis of maleic hydrazide in agricultural products by HPLC

被引：5

作者：

Kobayashi, M ^{[1
]}

Nagayama, T ^{[1
]}

Takano, I ^{[1
]}

Tamura, Y ^{[1
]}

Tateishi, Y ^{[1
]}

Tomizawa, S ^{[1
]}

Kimura, N ^{[1
]}

Kitayama, K ^{[1
]}

Saito, K ^{[1
]}

机构：

[1] Tokyo Metropolitan Res Lab Publ Hlth, Shinjuku Ku, Tokyo 1690073, Japan

来源：

JOURNAL OF THE FOOD HYGIENIC SOCIETY OF JAPAN | 2002年 / 43卷 / 06期

关键词：

maleic hydrazide; agricultural product; HPLC; herbicide; UV detector; LC/MS;

D O I：

10.3358/shokueishi.43.356

中图分类号：

TS2 [食品工业];

学科分类号：

0832 ;

摘要：

A simplified HPLC determination method for maleic hydrazide in agricultural products was developed, and commercial agricultural crops were investigated. The homogenate of agricultural products was extracted with water. The crude extract was purified on an ACCUCAT Bond Elut(R) extraction cartridge using water. Maleic hydrazide was analyzed by HPLC with UV detection (303 nm). The HPLC separation was performed on a ZORBAX SB-Aq column with acetonitrile-water-phosphoric acid (5: 95: 0.01) as the mobile phase. Recoveries of maleic hydrazide from 15 agricultural products fortified at 1.0 and 10 mug/g were in the ranges of 92.6similar to104.9% and 94.2similar to101.3%, respectively. The limit of detection was 0.5 mug/g in samples. The proposed method was applied to the determination of 242 commercial vegetables and fruits. Maleic hydrazide was detected in 2 samples of imported onion at the levels of 4.9 and 7.2 mug/g.

引用

页码：356 / 361

页数：6

共 50 条

[31] Theoretical Investigation of Solvation Effects on the Tautomerism of Maleic Hydrazide
Shabanian, Meisam
Moghanian, Hassan
Hajibeygi, Mohsen
Mohamadi, Azin
E-JOURNAL OF CHEMISTRY, 2012, 9 (01) : 107 - 112
[32] EFFECT OF MALEIC HYDRAZIDE ON THE TOTAL CHLOROPHYLL CONTENT OF SEAWEEDS
KALAISELVI, M
MANOHARAN, M
KATHIRESAN, K
JOURNAL OF ENVIRONMENTAL BIOLOGY, 1993, 14 (01): : 17 - 20
[33] Residues of free and bound maleic hydrazide in potato tubers
A. I. Dias
H. J. Duncan
Potato Research, 1999, 42 : 89 - 93
[34] Polymorph-specific chlorination of maleic-hydrazide
Katrusiak, A
Katrusiak, A
JOURNAL OF MOLECULAR STRUCTURE, 2003, 647 (1-3) : 203 - 210
[35] Simultaneous determination of residual phosphorus-containing amino acid herbicides in agricultural products by HPLC
Ohno, C
Otaki, M
Mori, Y
Hisamatsu, Y
Nakazawa, H
JOURNAL OF THE FOOD HYGIENIC SOCIETY OF JAPAN, 1999, 40 (01): : 75 - 79
[36] Photocatalysed degradation of a herbicide derivative, maleic hydrazide in aqueous suspensions of TiO2
Singh, HK
Muneer, M
Bahnemann, DW
JOURNAL OF ADVANCED OXIDATION TECHNOLOGIES, 2004, 7 (02) : 184 - 190
[37] Validation of an HPLC analytical method for determination of biogenic amines in agricultural products and monitoring of biogenic amines in Korean fermented agricultural products
Yoon H.
Park J.H.
Choi A.
Hwang H.-J.
Mah J.-H.
Toxicological Research, 2015, 31 (3) : 299 - 305
[38] PLANT METABOLIC STUDIES OF THE GROWTH-REGULATOR MALEIC HYDRAZIDE
KOMOSSA, D
SANDERMANN, H
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1995, 43 (10) : 2713 - 2715
[39] Rapid detection of maleic hydrazide based on the hydrogel SERS platform
Fu, Xiaolong
Su, Bihang
Xu, Jinhua
Pan, Cheng
Huang, Shuping
Fu, Fengfu
Lin, Zhenyu
Dong, Yongqiang
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2025, 325
[40] COMPARISON FOR DETERMINATION METHOD OF 9 KINDS OF HERBICIDES CONTAINING NITROGEN IN AGRICULTURAL PRODUCTS BETWEEN BY GC AND HPLC
TONOGAI, Y
TSUMURA, Y
NAKAMURA, Y
FUJIWARA, S
FUJII, Y
ITO, Y
EISEI KAGAKU-JAPANESE JOURNAL OF TOXICOLOGY AND ENVIRONMENTAL HEALTH, 1991, 37 (06): : 480 - 488

← 1 2 3 4 5 →