Single-Atom-Based Vanadium Oxide Catalysts Supported on Metal Organic Frameworks: Selective Alcohol Oxidation and Structure Activity Relationship

被引：194

作者：

Otake, Ken-ichi ^{[1
]}

Cui, Yuexing ^{[1
]}

Buru, Cassandra T. ^{[1
]}

Li, Zhanyong ^{[1
]}

Hupp, Joseph T. ^{[1
]}

Farha, Omar K. ^{[1
,2
]}

机构：

[1] Northwestern Univ, Dept Chem & Chem & Biol Engn, 2145 Sheridan Rd, Evanston, IL 60208 USA

[2] King Abdulaziz Univ, Fac Sci, Dept Chem, Jeddah 21589, Saudi Arabia

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2018年 / 140卷 / 28期

基金：

美国国家科学基金会;

关键词：

SITE HETEROGENEOUS CATALYSTS; COBALT CATALYSTS; COORDINATION POLYMERS; MODEL CATALYST; DEHYDROGENATION; NODES; WATER; HYDROGENATION; SPECTROSCOPY; CHEMISTRY;

D O I：

10.1021/jacs.8b05107

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report the syntheses, structures, and oxidation catalytic activities of a single-atom-based vanadium oxide incorporated in two highly crystalline MOFs, Hf-MOF-808 and Zr-NU-1000. These vanadium catalysts were introduced by a postsynthetic metalation, and the resulting materials (Hf-MOF-808-V and Zr-NU1000-V) were thoroughly characterized through a combination of analytic and spectroscopic techniques including single-crystal X-ray crystallography. Their catalytic properties were investigated using the oxidation of 4-methoxybenzyl alcohol under an oxygen atmosphere as a model reaction. Crystallographic and variable temperature spectroscopic studies revealed that the incorporated vanadium in Hf-MOF-808-V changes position with heat, which led to improved catalytic activity.

引用

页码：8652 / 8656

页数：5

共 46 条

[11] DEACTIVATION AND COMPOUND FORMATION IN SULFURIC-ACID CATALYSTS AND MODEL SYSTEMS [J].

ERIKSEN, KM ;

KARYDIS, DA ;

BOGHOSIAN, S ;

FEHRMANN, R .

JOURNAL OF CATALYSIS, 1995, 155 (01) :32-42

[12] A Highly Stable Zeotype Mesoporous Zirconium Metal-Organic Framework with Ultralarge Pores [J].

Feng, Dawei ;

Wang, Kecheng ;

Su, Jie ;

Liu, Tian-Fu ;

Park, Jihye ;

Wei, Zhangwen ;

Bosch, Mathieu ;

Yakovenko, Andrey ;

Zou, Xiaodong ;

Zhou, Hong-Cai .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (01) :149-154

[13] Large breathing effects in three-dimensional porous hybrid matter: facts, analyses, rules and consequences [J].

Ferey, Gerard ;

Serre, Christian .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1380-1399

[14] Water Adsorption in Porous Metal-Organic Frameworks and Related Materials [J].

Furukawa, Hiroyasu ;

Gandara, Felipe ;

Zhang, Yue-Biao ;

Jiang, Juncong ;

Queen, Wendy L. ;

Hudson, Matthew R. ;

Yaghi, Omar M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (11) :4369-4381

[15] The Chemistry and Applications of Metal-Organic Frameworks [J].

Furukawa, Hiroyasu ;

Cordova, Kyle E. ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

SCIENCE, 2013, 341 (6149) :974-+

[16] Solvent-Induced Assembly of Sliver Coordination Polymers (CPs) as Cooperative Catalysts for Synthesizing of Cyclopentenone[b]pyrroles Frameworks [J].

Huang, Chao ;

Han, Xiao ;

Shao, ZhiChao ;

Gao, Kuan ;

Liu, Mengjia ;

Wang, Yanjie ;

Wu, Jie ;

Hou, Hongwei ;

Mi, Liwei .

INORGANIC CHEMISTRY, 2017, 56 (09) :4874-4884

[17] Postsynthetic Tuning of Metal-Organic Frameworks for Targeted Applications [J].

Islamoglu, Timur ;

Goswami, Subhadip ;

Li, Zhanyong ;

Howarth, Ashlee J. ;

Farha, Omar K. ;

Hupp, Joseph T. .

ACCOUNTS OF CHEMICAL RESEARCH, 2017, 50 (04) :805-813

[18] Trivalent Zirconium and Hafnium Metal-Organic Frameworks for Catalytic 1,4-Dearomative Additions of Pyridines and Quinolines [J].

Ji, Pengfei ;

Feng, Xuanyu ;

Veroneau, Samuel S. ;

Song, Yang ;

Lin, Wenbin .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (44) :15600-15603

[19] Single-Site Cobalt Catalysts at New Zr12(μ3-O)8(μ3-OH)8(μ2-OH)6 Metal-Organic Framework Nodes for Highly Active Hydrogenation of Nitroarenes, Nitriles, and Isocyanides [J].

Ji, Pengfei ;

Manna, Kuntal ;

Lin, Zekai ;

Feng, Xuanyu ;

Urban, Ania ;

Song, Yang ;

Lin, Wenbin .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (20) :7004-7011

[20] Single-Site Cobalt Catalysts at New Zr8(μ2-O)8(μ2-OH)4 Metal-Organic Framework Nodes for Highly Active Hydrogenation of Alkenes, (mines, Carbonyls, and Heterocycles [J].

Ji, Pengfei ;

Manna, Kuntal ;

Lin, Zekai ;

Urban, Ania ;

Greene, Francis X. ;

Lan, Guangxu ;

Lin, Wenbin .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (37) :12234-12242

← 1 2 3 4 5 →