Photoelectron transfer from excited-state ruthenium(II) tris(bipyridyl) to methylviologen in an ionic liquid

被引：110

作者：

Gordon, CM

McLean, AJ

机构：

[1] Univ Strathclyde, Dept Pure & Appl Chem, Glasgow G1 1XL, Lanark, Scotland

[2] Univ Paisley, Dept Chem & Chem Engn, Paisley PA1 2BE, Renfrew, Scotland

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 15期

关键词：

D O I：

10.1039/b003754k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The temperature dependence of bimolecular rate constant and product cage escape yields for the photoelectron transfer reaction between [Ru(bpy)(3)](2+) and MV2+ in the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate is reported.

引用

页码：1395 / 1396

页数：2

共 14 条

[11] Electrochemical properties of imidazolium salt electrolytes for electrochemical capacitor applications [J].

McEwen, AB ;

Ngo, HL ;

LeCompte, K ;

Goldman, JL .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (05) :1687-1695

[12] A WEAK DELTA-G-DEGREES DEPENDENCE OF BACK ELECTRON-TRANSFER WITHIN THE GEMINATE REDOX PAIRS FORMED IN THE QUENCHING OF EXCITED RUTHENIUM(II) COMPLEXES BY METHYLVIOLOGEN [J].

OHNO, T ;

YOSHIMURA, A ;

PRASAD, DR ;

HOFFMAN, MZ .

JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (12) :4723-4728

[13] OXIDATIVE QUENCHING OF THE EXCITED-STATE OF TRIS(2,2'-BIPYRIDINE)RUTHENIUM(2+) ION BY METHYLVIOLOGEN - VARIATION OF SOLUTION MEDIUM AND TEMPERATURE [J].

SUN, H ;

YOSHIMURA, A ;

HOFFMAN, MZ .

JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (19) :5058-5064

[14] Room-temperature ionic liquids. Solvents for synthesis and catalysis [J].

Welton, T .

CHEMICAL REVIEWS, 1999, 99 (08) :2071-2083

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