Enantioselective hydroacylation of olefins with rhodium catalysts

被引：101

作者：

Murphy, Stephen K. ^{[1
,2
]}

Dong, Vy M. ^{[2
]}

机构：

[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

[2] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 89期

关键词：

DIRECT INTERMOLECULAR HYDROACYLATION; INTRAMOLECULAR HYDROACYLATION; HOMOGENEOUS CATALYSIS; COOPERATIVE CATALYSIS; ALDEHYDES; MECHANISM; 4-PENTENALS; ALKENE; SALICYLALDEHYDES; PENT-4-ENALS;

D O I：

10.1039/c4cc02276a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Over thirty years ago, James and Young reported the first enantioselective olefin hydroacylation by using rhodium catalysts. This viewpoint highlights the advances in this area, including 4-pentenal cyclisations, medium-ring syntheses, and intermolecular variants. © Partner Organisations 2014.

引用

页码：13645 / 13649

页数：5

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