Synthesis of gold(III) complexes with the 1,2-dithiolate-o-carborane ligand.: Crystal structures of [N(PPh3)2][AuCl2(S2C2B10H10)] and [AuCl(S2C2B10H10)(CH2PPh3)]

被引：20

作者：

Crespo, O

Gimeno, MC

Jones, PG

Laguna, A ^{[1
]}

机构：

[1] Univ Zaragoza, CSIC, Inst Ciencia Mat Aragon, Dept Quim Inorgan, E-50009 Zaragoza, Spain

[2] Tech Univ Carolo Wilhelmina Braunschweig, Inst Anorgan & Analyt Chem, D-38023 Braunschweig, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 547卷 / 01期

关键词：

gold(III); dithiolate complexes; o-carborane; X-ray structure;

D O I：

10.1016/S0022-328X(97)00268-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of 1,2-dithiol-o-carborane, under basic conditions, with trans-NBu4[AuCl2R2] or [N(PPh3)(2)][AuCl4] results in the formation of the anionic gold(III) derivatives NBu4[(AuR2(S2C2B10H10)] [R = C6F5 (1), C6F3H2 (2)] or [N(PPh3)(2)][AuCl2(S2C2B10H10)] (3). Neutral gold(III) species are synthesized from suitable starting materials such as [AuCl3L] or [AuCl2X(PPh3)], leading to the complexes [AuCl(S2C2B10H10)L] [L = CH2PPh3 (4), CH2PPh2Me (5)] or [AuX(S2C2B10H10)(PPh3)][X = Cl (6), C6F5 (7)]. Complexes 3 and 3 were characterized by X-ray diffraction studies. (C) 1997 Elsevier Science S.A.

引用

收藏

页码：89 / 95

页数：7

相关论文

共 50 条

[41] New Tetraruthenium Cluster from the Thermolysis of [Ru3(CO)10(μ-dppm)]: Crystal Structure of [HRu4(CO)9(μ3-PhPCH2PPh2) (μ3,η2:η1:η1-C6H4)] [J].

Md. Abdullah Al Mamun ;

Tazul Islam ;

Subas Rajbangshi ;

Shishir Ghosh ;

Michael G. Richmond ;

Shariff E. Kabir .

Journal of Chemical Crystallography, 2024, 54 :54-63

[42] C- and O-metallation of N-benzylideneamines by palladium .2. Synthesis and X-ray crystal structure of [Pd(2{CH=N-(CH2)(2)-4'-(MeO)C6H4}-4,5-(MeO)(2)C6H2)Br(PPh(3))] [J].

Albert, J ;

Granell, J ;

Moragas, R ;

FontBardia, M ;

Solans, X .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 522 (01) :59-67

[43] A bimetallic oxide framework, [{Cu(bpy)}2Mo4O10(O3PCH2C6H4CH2PO3)2], constructed from novel {Mo4O10(O3PR)4}n4n- chains [J].

Jones, Stephanie ;

Liu, Hongxue ;

Schmidtke, Katherine ;

O'Connor, Charles C. ;

Zubieta, Jon .

INORGANIC CHEMISTRY COMMUNICATIONS, 2010, 13 (02) :298-301

[44] Reactivity of Two 16e Half-Sandwich Cobalt Complexes Containing 1,2-Dicarba-closo-Dodecaborane-1,2-Dichalcogenolate (E2C2B10H10)2- (E = S, Se) Units toward Triphenylphosphine [J].

Ye, H. D. ;

Zhan, Y. L. ;

Liang, J. ;

Ye, T. Y. ;

Zhang, D. ;

Peng, H. N. ;

Hu, J. R. .

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2018, 44 (07) :454-459

[45] Synthesis, characterization and crystal structure of the bimetallic cyano-bridged [(η5-C5H5)(PPh3)2Ru(μ-CN)Ru(PPh3)2(η5-C5H5)][PF6] [J].

Ornelas, C ;

Gandum, C ;

Mesquita, J ;

Rodrigues, J ;

Garcia, MH ;

Lopes, N ;

Robalo, MP ;

Nättinen, K ;

Rissanen, K .

INORGANICA CHIMICA ACTA, 2005, 358 (08) :2482-2488

[46] CYCLOMETALATED PLATINUM(II) AND PLATINUM(IV) COMPOUNDS OF N-BENZYLIDENE-2-CHLOROBENZYLAMINE - CRYSTAL-STRUCTURE OF [PTME(PPH3)(C6H4CH=NCH2C6H4CL-2)] [J].

CRESPO, M ;

SOLANS, X ;

FONTBARDIA, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 483 (1-2) :187-192

[47] Iron carbonyl complexes bearing phenazine and acridine ligands: X-ray structures of Fe(CO)3(η4-C12H8N2), Fe(CO)2{P(OMe)3}(η4-C12H8N2), Fe(CO)2(PPh3) (η4-C13H9N), and Fe(CO)2(κ1-dppm) (η4-C12H8N2) [J].

Chowdhury, Md. Arshad H. ;

Rahman, Md. Saifur ;

Islam, Md. Rakibul ;

Rajbangshi, Subas ;

Ghosh, Shishir ;

Hogarth, Graeme ;

Tocher, Derek A. ;

Yang, Li ;

Richmond, Michael G. ;

Kabir, Shariff E. .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2016, 805 :34-41

[48] Dinuclear cyclometallated complexes of Pd-II with diphosphines. X-ray crystal structure of [1,4-{Pd[2,4-(MeO)(2)C6H2C(H)=N]}(2)-C6H4{Ph(2)P(CH2)(3)PPh(2)-P,P}(2)][PF6](2) [J].

Vila, JM ;

Gayoso, M ;

Torres, ML ;

Fernandez, JJ ;

Fernandez, A ;

Ortigueira, JM ;

Bailey, NA ;

Adams, H .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 511 (1-2) :129-138

[49] Synthesis and crystal structures of the novel tetrameric nitrido complexes [{cyelo-ReN}4(S2CNEt2) 6(MeOH)2(PPh3)2][BPh4]2..CH2Cl2.2H2O and [{cyclo-ReN}4(S2CNEt2)4Cl4(PMe2Ph)4].2 acetone [J].

Griffiths, DV ;

Parrott, SJ ;

Togrou, M ;

Dilworth, JR ;

Zheng, YF ;

Ritter, S ;

Abram, U .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1998, 624 (09) :1409-1414

[50] Mild C-H activation of activated aromatics with [8,8′-μ-I-3,3′-Co(1,2-C2B9H10)2]: Just mix them [J].

Kosenko, Irina D. ;

Lobanova, Irina A. ;

Godovikov, Ivan A. ;

Starikova, Zoya A. ;

Sivaev, Igor B. ;

Bregadze, Vladimir I. .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2012, 721 :70-77

← 1 2 3 4 5 →