Novel odd/even effect of alkylene chain length on the photopolymerizability of organogelators

被引:63
作者
Aoki, K [1 ]
Kudo, M [1 ]
Tamaoki, N [1 ]
机构
[1] Natl Inst Adv Ind Sci & Technol, Nanotechnol Res Inst, Tsukuba, Ibaraki 3058565, Japan
关键词
D O I
10.1021/ol048364+
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Starting from diactylene diacarboxylic acids, we have synthesized a series of photopolymerizable organogelators that possess simple amide structures, different alkylene chain lengths, and either optically active or racemic 3,7-dimethyl-1-octylamine units. The alkylene chain length of these compounds exhibits a prominent odd/even effect with respect to the photopolymerization in the gel state and is accompanied by a stereostructural effect on the gelation ability.
引用
收藏
页码:4009 / 4012
页数:4
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