The X-ray crystal structure, conformation and preparation of anti-3,3,6,6-tetramethylthiepane-4,5-diol: stereochemistry of reduction of a heterocyclic alpha-hydroxy ketone

被引：3

作者：

Feeder, N

Ginnelly, MJ

Jones, RVH

OSullivan, S

Warren, S

Wyatt, P

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,CAMBRIDGE CB2 1EW,ENGLAND

[2] ZENECA GRANGEMOUTH WORKS,PROC TECHNOL DEPT,GRANGEMOUTH FK3 8XG,SCOTLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1997年 / 22期

关键词：

D O I：

10.1039/a605572i

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The X-ray crystal structure and conformation of the anti title diol is described together with stereoselective syntheses of syn- and anti-diols from a readily available acyloin. Some control of the stereoselective reduction of alpha-hydroxy ketones by chelating and non-chelating reducing agents is possible.

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页码：3479 / 3483

页数：5

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