Petrogenetic evolution of early Paleozoic trachytic rocks in the South Qinling Belt, Central China: Insights from mineralogy, geochemistry, and thermodynamic modeling

Early Paleozoic volcanic-intrusive rocks in the South Qinling Belt, central China, consist of bimodal alkaline suites ranging in composition from basalt to trachyte, with an apparent scarcity of intermediate silicic components (the so-called "Daly gap "). A series of trachytic rocks have been identified in the Quanxi area of the South Qinling Belt. In this work, we combine mineralogical evidence with whole-rock major-and trace-element data, Sr-Nd-Pb isotope data, and the results of thermodynamic modeling to gain a better understanding of the petrogenesis and evolutionary process of the Quanxi trachytic rocks, as well as their compositional discontinuity with coeval mafic rocks. Our samples can be clearly classified into two lithological groups based on their phenocryst content: Group 1, phenocryst-poor trachytes (< 5 vol% phenocrysts; SiO2 = 63.91-66.13 wt%) and Group 2, trachytic tufflavas (30-45 vol% pyroclasts; SiO2 = 53.34-59.03 wt%). All of the samples exhibit typical oceanic island basalt-like enrichment in light rare earth elements and high field strength elements, as well as marked depletion of Ba, Sr, and Ti. A cogenetic metasomatized lithosphere source for the Quanxi trachytic rocks and contemporaneous mafic rocks is indicated by their homogeneous isotopic features (epsilon(Nd)(t) = +2.3 to +3.4; initial Pb-206/Pb-204 = 17.92-18.69; initial Pb-207/Pb-204 = 15.53-15.57; initial Pb-208/Pb-204 = 37.96-38.99) and linear geochemical variations, with protracted fractional crystallization regarded as the key mechanism for the compositional variations among these cogenetic rocks. The results of Rhyolite-MELTS modeling predict 72%-80% crystallization involving plagioclase, pyroxene, biotite, apatite, and Fe-Ti oxide, to yield the magmatic compositions from an evolved mafic progenitor to the Quanxi trachytes under conditions of low pressure (1.5-2 kbar), high H2O content (2-3 wt%), and high fO(2) (FMQ-0.5). Some incompatible elements in trachytic tufflavas deviate markedly from the liquid lines of descent from coeval mafic rocks to the Quanxi trachytes: this deviation is attributed to a combination of the involvement of large proportions of alkali-feldspar pyroclasts and post magmatic hydrothermal alteration. The presence of the "Daly gap " in early Paleozoic alkaline suites can be explained by an accelerated differentiation rate (i.e., dSiO(2)/dt) in the SiO2-intermediate field, which is driven by the simultaneous separation of a considerable scale of SiO2-poor phases.