Analysis of Organic Light-Emitting Diode As a Maxwell-Wagner Effect Element by Time-Resolved Optical Second Harmonic Generation Measurement

被引:44
作者
Taguchi, Dai [1 ]
Inoue, Shio [1 ]
Zhang, Le [1 ]
Li, Jun [1 ]
Weis, Martin [1 ]
Manaka, Takaaki [1 ]
Iwamoto, Mitsumasa [1 ]
机构
[1] Tokyo Inst Technol, Dept Phys Elect, Meguro Ku, Tokyo 1528552, Japan
来源
JOURNAL OF PHYSICAL CHEMISTRY LETTERS | 2010年 / 1卷 / 05期
关键词
TRANSIENT ELECTROLUMINESCENCE; INJECTION; MOBILITY; LAYER;
D O I
10.1021/jz1000215
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
An organic light-emitting diode (OLED) was analyzed as a system of the Maxwell-Wagner effect element, by using time-resolved optical second harmonic generation (SHG) measurement. A transient SHG signal generated from N,N'-di-[(1-naphthyl)-N,N'-diphenyl]-(1,1'-biphenyl)-4,4'-diamine (alpha-NPD) layer in an indium zinc oxide (IZO)/alpha-NPD/tris(8-hydroxy-quinolinato) aluminum(III) (Alq3)/LiF/Al OLED device was selectively probed with applying alternating current (AC) square wave voltage, and the electric field distribution change in the device was examined. Results showed that charge Q(s) at the alpha-NPD/Alq3 interface changed in accordance with charging and discharging processes accompanied by electroluminescence (EL). We found that observed SHG response reflected well charging and discharging of carriers on electrodes and carrier transit across alpha-NPD and Alq3 layers, and accounted for nonreversal charging and discharging processes.
引用
收藏
页码:803 / 807
页数:5
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