Synthesis and characterization of a dipyriamethyrin-uranyl complex

被引：31

作者：

Brewster, James T., II ^{[1
]}

He, Qing ^{[1
]}

Anguera, Gonzalo ^{[1
]}

Moore, Matthew D. ^{[1
]}

Ke, Xian-Sheng ^{[1
]}

Lynch, Vincent M. ^{[1
]}

Sessler, Jonathan L. ^{[1
]}

机构：

[1] Univ Texas Austin, Dept Chem, 105 East 24th,St Stop A5300, Austin, TX 78712 USA

来源：

CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 36期

关键词：

TRANSITION-METAL-COMPLEXES; EXPANDED PORPHYRINS; PYRIDINE; HEXAPHYRIN(1.0.1.0.0.0); MACROCYCLE; ASSEMBLIES;

D O I：

10.1039/c7cc01674c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction between non-aqueous uranyl silylamide (UO2[N(SiMe3)(2)](2)center dot 2THF) under anaerobic conditions or uranyl acetate (UO2(OAc)(2)center dot 2H(2)O) under standard laboratory conditions and dipyriamethryin affords a bench-stable uranyl complex. Competition studies as well as DFT calculations provide support for the observed selectivity for the uranyl cation over trivalent lanthanide and multiple transition metal precursors.

引用

页码：4981 / 4984

页数：4

共 43 条

[1] A new synthesis of isoamethyrins: A 4+2 route [J].

Anguera, Gonzalo ;

Borros, Salvador ;

Borrell, Jose I. ;

Sanchez-Garcia, David .

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 2016, 20 (8-11) :1055-1059

[2]

[Anonymous], 2014, ANGEW CHEM

[3] DENSITY-FUNCTIONAL THERMOCHEMISTRY .3. THE ROLE OF EXACT EXCHANGE [J].

BECKE, AD .

JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (07) :5648-5652

[4] A trigonal bipyramidal uranyl amido complex:: Synthesis and structural characterization of [Na(THF)2] [UO2(N(SiMe3)2)3] [J].

Burns, CJ ;

Clark, DL ;

Donohoe, RJ ;

Duval, PB ;

Scott, BL ;

Tait, CD .

INORGANIC CHEMISTRY, 2000, 39 (24) :5464-5468

[5] Convenient access to the anhydrous thorium tetrachloride complexes ThCl4(DME)2, ThCl4(1,4-dioxane)2 and ThCl4(THF)3.5 using commercially available and inexpensive starting materials [J].

Cantat, Thibault ;

Scott, Brian L. ;

Kiplinger, Jaqueline L. .

CHEMICAL COMMUNICATIONS, 2010, 46 (06) :919-921

[6] AMINOSILANES IN ORGANIC-SYNTHESIS - PREPARATION OF NEW EXPANDED PORPHYRIN LIGANDS AND BIMETALLIC TRANSITION-METAL COMPLEXES - CRYSTAL-STRUCTURE OF A TETRAPYRROLE MACROCYCLE DIRHODIUM COMPLEX [J].

CARRE, FH ;

CORRIU, RJP ;

BOLIN, G ;

MOREAU, JJE ;

VERNHET, C .

ORGANOMETALLICS, 1993, 12 (07) :2478-2486

[7] A FACILE SYNTHESIS OF NEW TETRAPYRROLE MACROCYCLIC DERIVATIVES - FORMATION OF BIMETALLIC TRANSITION-METAL COMPLEXES [J].

CORRIU, RJP ;

BOLIN, G ;

MOREAU, JJE ;

VERNHET, C .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (04) :211-213

[8] Multiporphyrinic Cages: Architectures and Functions [J].

Durot, Stephanie ;

Taesch, Julien ;

Heitz, Valerie .

CHEMICAL REVIEWS, 2014, 114 (17) :8542-8578

[9]

Frisch M.J., 2016, Gaussian, V16

[10] An Unusual Cobalt Azide Adduct That Produces a Nitrene Species for Carbon-Hydrogen Insertion Chemistry [J].

Grant, Lauren N. ;

Carroll, Maria E. ;

Carroll, Patrick J. ;

Mindiola, Daniel J. .

INORGANIC CHEMISTRY, 2016, 55 (16) :7997-8002

← 1 2 3 4 5 →