Effects of Ce3+ ions on the photoluminescence properties of Sr2SiO4:Eu2+ phosphors

被引:12
作者
Wu, Tingting [1 ]
Meng, Fanlong [1 ]
Du, Ying [1 ]
Tian, Yanna [1 ]
Ma, Jing [1 ]
Bai, Zhaohui [1 ]
Zhang, Xiyan [1 ]
机构
[1] Changchun Univ Sci & Technol, Sch Mat Sci & Engn, Changchun 130022, Peoples R China
基金
中国国家自然科学基金;
关键词
WHITE-LIGHT GENERATION; LUMINESCENCE PROPERTIES; ENERGY-TRANSFER; RED PHOSPHORS; ULTRAVIOLET; LEDS; NANOPHOSPHOR;
D O I
10.1007/s10854-017-6840-7
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
In this paper, Sr2SiO4:Eu2+ and Sr2SiO4:Eu2+,doped with Ce3+ phosphors were synthesized by high-temperature solid-state reaction method sintered at 1250 A degrees C for 2h in reducing atmosphere. The phase of as-prepared samples was analyzed by X-ray diffraction (XRD). The results of the XRD patterns confirmed that the obtained phosphors were a single phase of Sr2SiO4 composed of orthorhombic structure. In addition, we changed the doped concentration of Eu2+, and characterized the luminescence properties of the samples by the fluorescence spectrophotometer. The results showed that when the Eu2+-doped concentration was 0.5 mol%, the luminous intensity of the samples was the highest, and the concentration quenching mechanism was the dipole-dipole interaction. This work has researched the sensitization effect of co-doping ions (Ce3+) to Sr2SiO4:Eu2+ phosphors. The results showed that the luminescence intensity of the samples improved when doped with Ce3+ ions, and reached the maximum when the concentration was 0.5 mol%. Furthermore, the energy transfer from Ce3+ to Eu2+ under UV excitation was demonstrated.
引用
收藏
页码:10645 / 10651
页数:7
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