The role of secondary interactions in the asymmetric palladium-catalysed hydrosilylation of olefins with monophosphane ligands

被引：78

作者：

Gibson, Susan E. ^{[1
]}

Rudd, Matthew ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2007年 / 349卷 / 06期

关键词：

alcohols; asymmetric catalysis; hydrosilylation; phosphane ligands; secondary interactions;

D O I：

10.1002/adsc.200600458

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A structure-activity survey of monophosphane ligands used in the asymmetric palladium-catalysed hydrosilylation reaction of olefins is presented and used to assess the role of secondary interactions on catalyst activity and selectivity.

引用

页码：781 / 795

页数：15

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