Biodiesel synthesis using chicken manure biochar and waste cooking oil

被引：43

作者：

Jung, Jong-Min ^{[1
]}

Lee, Sang-Ryong ^{[2
]}

Lee, Jechan ^{[1
]}

Lee, Taewoo ^{[1
]}

Tsang, Daniel C. W. ^{[3
]}

Kwon, Eilhann E. ^{[1
]}

机构：

[1] Sejong Univ, Environm & Energy Dept, Seoul 05006, South Korea

[2] Rural Dev Adm, Dept Anim Biotechnol & Environm, Natl Inst Anim Sci, Wanju Gun 55365, South Korea

[3] Hong Kong Polytech Univ, Dept Civil & Environm Engn, Kowloon, Hong Kong, Peoples R China

来源：

BIORESOURCE TECHNOLOGY | 2017年 / 244卷

基金：

新加坡国家研究基金会;

关键词：

Chicken manure; Biochar; Pseudo-catalytic transesterification; Biodiesel; Waste cooking oil; LIFE-CYCLE ASSESSMENT; PYROGENIC TRANSFORMATION; BIOMASS; CATALYST; LIPASE; EXTRACTION; ALLOCATION; BIOENERGY; ESTERS; STEP;

D O I：

10.1016/j.biortech.2017.08.044

中图分类号：

S2 [农业工程];

学科分类号：

0828 ;

摘要：

This study laid an emphasis on the possible employment of biochar generated from pyrolysis of chicken manure to establish a green platform for producing biodiesel. To this end, the pseudo-catalytic transesterification reaction using chicken manure biochar and waste cooking oil was investigated. Compared with a commercial porous material (SiO2), chicken manure biochar generated from 350 degrees C showed better performance, resulting in 95.6% of the FAME yield at 350 degrees C. The Ca species in chicken manure biochar imparted strong catalytic capability by providing the basicity for transesterification. The identified catalytic effect also led to the thermal cracking of unsaturated FAMEs, which decreased the overall FAME yield. For example, 40-60% of converted FAMEs were thermally degraded. To avoid undesirable thermal cracking arising from the high content of the Ca species in chicken manure biochar, the fabrication of chicken manure biochar at temperatures >= 350 degrees C was highly recommended.

引用

页码：810 / 815

页数：6

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