Synthesis of quinolines via ruthenium-catalysed amine exchange reaction between anilines and trialkylamines

被引:173
作者
Cho, CS [1 ]
Oh, BH [1 ]
Kim, JS [1 ]
Kim, TJ [1 ]
Shim, SC [1 ]
机构
[1] Kyungpook Natl Univ, Coll Engn, Dept Ind Chem, Taegu 702701, South Korea
关键词
D O I
10.1039/b005966h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Anilines react with an array of trialkylamines in the presence of a catalytic amount of RuCl3. nH(2)O and bis(diphenylphosphino)methane together with SnCl2. 2H(2)O and hex-1-ene as hydrogen acceptor in dioxane at 180 degrees C to afford the corresponding 2,3-disubstituted quinolines in moderate to good yields.
引用
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页码:1885 / 1886
页数:2
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