From clusters to phase diagrams: composition rules of quasicrystals and bulk metallic glasses

被引:246
作者
Dong, C. [1 ]
Wang, Q. [1 ]
Qiang, J. B. [1 ]
Wang, Y. M. [1 ]
Jiang, N. [1 ]
Han, G. [1 ]
Li, Y. H. [1 ]
Wu, J. [1 ]
Xia, J. H. [1 ]
机构
[1] Dalian Univ Technol, State Key Lab Mat Modificat Laser Ion & Electron, Dalian 116024, Peoples R China
关键词
D O I
10.1088/0022-3727/40/15/R01
中图分类号
O59 [应用物理学];
学科分类号
摘要
Metallic elements having negative enthalpies of mixing tend to form characteristic local atomic clusters. In this review, we use the structural information in the first nearest neighbour shell level, or first-shell atomic cluster, to derive the composition rules of two types of complex alloy phases, quasicrystals and bulk metallic glasses, both being composed of elements with negative enthalpies of mixing. We first show the composition phenomena in quasicrystal-forming systems, where major composition rules such as cluster line, electron concentration and atomic size criteria are derived. Then we analyse the composition rules of bulk metallic glasses using the very same approaches. Finally, we summarize their common composition rules into more general rules and basic theories.
引用
收藏
页码:R273 / R291
页数:19
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