Application of heterogeneous colloid catalysts for the preparation of fine chemicals

被引：62
|
作者：
Bonnemann, H [1 ]
Brijoux, W [1 ]
Tilling, AS [1 ]
Siepen, K [1 ]
机构：
[1] Max Planck Inst Kohlenforsch, D-45466 Mulheim, Germany
来源：
TOPICS IN CATALYSIS | 1997年 / 4卷 / 3-4期
关键词：
metal-colloid catalysts; selective cis-hydrogenation; leaf alcohol; glucose-oxidation;
D O I：
10.1023/A:1019152625358
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Preprepared nanometals stabilized by surfactants may be used as precursors for a new type of heterogeneous catalyst. Independent of the support these mono-or plurimetallic precursors may be optimized dependent on the size, composition, and structure of the particles. Further, the active metal surface may be shielded against poisons by the protective shed.-In addition, doping agents may be used in older to enhance the catalytic performance. The cia-selective partial hydrogenation of 3-hexyn-1-ol giving leaf alcohol, a valuable fragrance, and the selective oxidation of glucose giving sodium gluconate are current examples for the application of supported nanometal colloids in fine chemicals catalysis.
引用
收藏
页码：217 / 227
页数：11
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