Application of heterogeneous colloid catalysts for the preparation of fine chemicals

被引：62

作者：

Bonnemann, H ^{[1
]}

Brijoux, W ^{[1
]}

Tilling, AS ^{[1
]}

Siepen, K ^{[1
]}

机构：

[1] Max Planck Inst Kohlenforsch, D-45466 Mulheim, Germany

来源：

TOPICS IN CATALYSIS | 1997年 / 4卷 / 3-4期

关键词：

metal-colloid catalysts; selective cis-hydrogenation; leaf alcohol; glucose-oxidation;

D O I：

10.1023/A:1019152625358

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Preprepared nanometals stabilized by surfactants may be used as precursors for a new type of heterogeneous catalyst. Independent of the support these mono-or plurimetallic precursors may be optimized dependent on the size, composition, and structure of the particles. Further, the active metal surface may be shielded against poisons by the protective shed.-In addition, doping agents may be used in older to enhance the catalytic performance. The cia-selective partial hydrogenation of 3-hexyn-1-ol giving leaf alcohol, a valuable fragrance, and the selective oxidation of glucose giving sodium gluconate are current examples for the application of supported nanometal colloids in fine chemicals catalysis.

引用

页码：217 / 227

页数：11

共 35 条

[1] CATALYTIC-OXIDATION OF GLUCOSE ON BISMUTH-PROMOTED PALLADIUM CATALYSTS [J].

BESSON, M ;

LAHMER, F ;

GALLEZOT, P ;

FUERTES, P ;

FLECHE, G .

JOURNAL OF CATALYSIS, 1995, 152 (01) :116-121

[2] Nanoscale colloidal metals and alloys stabilized by solvents and surfactants - Preparation and use as catalyst precursors [J].

Bonnemann, H ;

Braun, G ;

Brijoux, W ;

Brinkmann, R ;

Tilling, AS ;

Seevogel, K ;

Siepen, K .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 520 (1-2) :143-162

[3] HIGHLY DISPERSED METAL-CLUSTERS AND COLLOIDS FOR THE PREPARATION OF ACTIVE LIQUID-PHASE HYDROGENATION CATALYSTS [J].

BONNEMANN, H ;

BRIJOUX, W ;

BRINKMANN, R ;

DINJUS, E ;

FRETZEN, R ;

JOUSSEN, T ;

KORALL, B .

JOURNAL OF MOLECULAR CATALYSIS, 1992, 74 (1-3) :323-333

[4] PREPARATION, CHARACTERIZATION, AND APPLICATION OF FINE METAL PARTICLES AND METAL COLLOIDS USING HYDROTRIORGANOBORATES [J].

BONNEMANN, H ;

BRIJOUX, W ;

BRINKMANN, R ;

FRETZEN, R ;

JOUSSEN, T ;

KOPPLER, R ;

KORALL, B ;

NEITELER, P ;

RICHTER, J .

JOURNAL OF MOLECULAR CATALYSIS, 1994, 86 (1-3) :129-177

[5] FORMATION OF COLLOIDAL TRANSITION-METALS IN ORGANIC PHASES AND THEIR APPLICATION IN CATALYSIS [J].

BONNEMANN, H ;

BRIJOUX, W ;

BRINKMANN, R ;

DINJUS, E ;

JOUSSEN, T ;

KORALL, B .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (10) :1312-1314

[6]

BONNEMANN H, 1995, Z NATURFORSCH B, V50, P333

[7] PREPARATION AND CATALYTIC PROPERTIES OF NR4+-STABILIZED PALLADIUM COLLOIDS [J].

BONNEMANN, H ;

BRINKMANN, R ;

NEITELER, P .

APPLIED ORGANOMETALLIC CHEMISTRY, 1994, 8 (04) :361-378

[8]

Bonnemann H., 1991, ANGEW CHEM, V103, P1344

[9]

BONNEMANN H, 1997, IN PRESS INORGANICA

[10]

BONNEMANN H, 1996, ADV CATALYSTS NANOST, P165

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