Volumetric properties of starch-water mixtures

被引:8
作者
Benczedi, D
Tomka, I
Panayiotou, C [1 ]
机构
[1] Univ Thessaloniki, Dept Chem Engn, GR-54006 Salonika, Greece
[2] Firmenich Co, Div Res, CH-1211 Geneva 8, Switzerland
[3] ETH Zentrum, Inst Polymere, CH-8092 Zurich, Switzerland
关键词
equation of state; PVT data; hydrogen bonding; mixture; starch;
D O I
10.1016/S0378-3812(97)00165-9
中图分类号
O414.1 [热力学];
学科分类号
摘要
The specific volumes of extruded amorphous starch and its aqueous mixtures containing up to 30 wt.% were investigated between 25 and 160 degrees C over an extended pressure range up to 100 MPa. The specific volume of water was also measured at the same temperature and pressure range. These highly non-ideal systems develop three-dimensional networks of hydrogen bonds, both in the pure state and in mixtures. The experimental data were correlated with the LFHB (lattice-fluid hydrogen-bonding) model. The model is able to describe satisfactorily the volumetric behavior of both pure components and their mixtures. (C) 1997 Elsevier Science B.V.
引用
收藏
页码:145 / 158
页数:14
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