An efficient oxidation of toluene over Co(II)TPP supported on chitosan using air

被引：33

作者：

Huang, Guan ^{[1
]}

Wang, Ai P. ^{[1
]}

Liu, Shang Y. ^{[1
]}

Guo, Yong A. ^{[1
]}

Zhou, Hong ^{[1
]}

Zhao, Shu K. ^{[1
]}

机构：

[1] Guangxi Univ, Coll Chem & Chem Engn, Nanning 530004, Peoples R China

来源：

CATALYSIS LETTERS | 2007年 / 114卷 / 3-4期

关键词：

chitosan; cobalt tetraphenylporphyrin; toluene oxidation; air;

D O I：

10.1007/s10562-007-9061-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An efficient oxidation of toluene to benzaldehyde and benzyl alcohol is accomplished over chitosan(CTS)-supported Co(II)TPP catalyst [Co(II)TPP/CTS] under a relatively mild reaction condition using air in absence of reductants and solvents, it can be reused for five times, with average selectivity of 65%, average toluene conversion of 8.83% and average turnover number of 69804.

引用

页码：174 / 177

页数：4

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