Anion Probe and Molecular Logic Gate Based on Tryptanthrin Derivative

被引：3

作者：

Wang Qingguo ^{[1
,2
]}

Li Dan ^{[1
]}

Lu Ning ^{[1
]}

Tong Dingyi ^{[1
]}

Zhuang Hejing ^{[1
]}

Li Fuqiu ^{[3
]}

Wang Lan ^{[4
]}

Duan Haifeng ^{[1
]}

Lin Yingjie ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, Changchun 130012, Peoples R China

[2] Daqing Oilfield Prod Technol Inst, Daqing 163453, Peoples R China

[3] Jilin Univ, Hosp 2, Changchun 130041, Peoples R China

[4] Jilin Univ, China Japan Union Hosp, Changchun 130033, Peoples R China

来源：

CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 2014年 / 35卷 / 10期

基金：

中国国家自然科学基金;

关键词：

Anion; Tryptanthrin; Molecular logic gate; SELECTIVE DETECTION; GOLD NANOPARTICLES; MERCURY IONS; FLUORESCENT; RECOGNITION; PB2+;

D O I：

10.7503/cjcu20140090

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A tryptanthrin derivative as anions probe was synthesized by the reaction of tryptanthrin with phenylhydrazine. In DMF, with the addition of F-, AcO- and H2PO4-, the "yellow-to-orange" change could be observed by naked eyes. Meanwhile, there were no changes when other anions(Cl-, Br-, I-, ClO4-, NO3- and HSO4-) were added. H-1 NMR titrations of this anions probe indicated that the "yellow-to-orange" response was triggered by the hydrogen bonding interaction between NH with F-, AcO- and H2PO4-. Then a novel four-input molecular logic gate was designed.

引用

页码：2114 / 2118

页数：5

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