Synthesis, chemical modification and second order non-linear optical properties of a new calixarene copolymer

被引:31
作者
Vocanson, F
Seigle-Ferrand, P
Lamartine, R
Fort, A
Coleman, AW
Shahgaldian, P
Mugnier, J
Zerroukhi, A
机构
[1] Univ Lyon 1, CNRS, SROMB, UMR 5078, F-69622 Villeurbanne, France
[2] CNRS, IPCMS, GONLO, UMR 7504, F-67034 Strasbourg 2, France
[3] Univ Lyon 1, IBCP, UMR 5086, CNRS, F-69367 Lyon 07, France
[4] Univ Lyon 1, CNRS, LPCML, UMR 5620, F-69622 Villeurbanne, France
[5] Univ St Etienne, Lab Rheol Mat Plast, FRE 2396, CNRS,Fac Sci & Tech, F-42023 St Etienne, France
关键词
D O I
10.1039/b302592f
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The synthesis of p-tert-butylcalix[4] arene containing polymerizable groups at the lower rim is reported. A calixarene monomer with one methacryloyloxy group at the phenolic rim was copolymerized with methyl methacrylate, yielding linear polymers with pendant calixarene groups in the cone conformation. Chemical modification of these macrocycles by ipso-nitration is described. Thin films were obtained from these materials and studied using m-lines spectroscopy, AFM, and NLO. These modified polymer films exhibited high and stable NLO responses.
引用
收藏
页码:1596 / 1602
页数:7
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