Photometric determination of gallium in the presence of aluminum

被引：1

作者：

Nagiev, Kh. D. ^{[1
]}

Kulieva, F. V. ^{[1
]}

Gambarov, D. G. ^{[1
]}

机构：

[1] Baku State Univ, Baku 370148, Azerbaijan

来源：

JOURNAL OF ANALYTICAL CHEMISTRY | 2007年 / 62卷 / 08期

关键词：

The complexation of gallium(III) with 2,2′,3,4-tetrahydroxy-3′- sulfo-5′-nitrobenzene in the presence of and without 1,10-phenanthroline was studied. In the presence of 1,10-phenanthroline, a mixed-ligand complex with the component ratio 1:2:1 and the stability constant logβ = 15.5 ± 0.2 is formed. The effect of pH, time, temperature, and the concentration of components on the formation of the binary and mixed-ligand complexes of gallium was studied. A procedure was developed for the photometric determination of gallium(III) in the presence of aluminum (III). © 2007 Pleiades Publishing, Ltd;

D O I：

10.1134/S1061934807080060

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The complexation of gallium(III) with 2,2',3,4-tetrahydroxy-3'-sulfo-5'-nitrobenzene in the presence of and without 1,10-phenanthroline was studied. In the presence of 1,10-phenanthroline, a mixed-ligand complex with the component ratio 1:2:1 and the stability constant log beta = 15.5 +/- 0.2 is formed. The effect of pH, time, temperature, and the concentration of components on the formation of the binary and mixed-ligand complexes of gallium was studied. A procedure was developed for the photometric determination of gallium(III) in the presence of aluminum (III).

引用

页码：730 / 732

页数：3