Single step reductive polymerization of functional 3,4-propylenedioxythiophenes via direct C-H arylation catalyzed by palladium acetate

被引:61
作者
Kumar, Anshu
Kumar, Anil [1 ]
机构
[1] Indian Inst Technol, Dept Chem, Bombay 400076, Maharashtra, India
关键词
ELECTROCHROMIC DIOXYTHIOPHENE POLYMERS; HIGH-CONTRAST; 3,4-ETHYLENEDIOXYTHIOPHENE EDOT; CONJUGATED POLYMERS; VISIBLE REGION; DERIVATIVES; PEDOT; POLY(3,4-ETHYLENEDIOXYTHIOPHENE); DEVICES;
D O I
10.1039/b9py00265k
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In this Communication we report a single step reductive polymerization of ProDOT derivatives which is compatible with functional side chains and is amenable for scale-up.
引用
收藏
页码:286 / 288
页数:3
相关论文
共 27 条
[1]   Specific recognition of a nucleobase-functionalized poly(3,4-ethylenedioxithiophene) (PEDOT) in aqueous media [J].
Blanco Bazaco, Raul ;
Gomez, Rafael ;
Seoane, Carlos ;
Baeuerle, Peter ;
Segura, Jose L. .
TETRAHEDRON LETTERS, 2009, 50 (28) :4154-4157
[2]   Solid-state conversion of processable 3,4-ethylenedioxythioplhene (EDOT) containing poly(arylsilane) precursors to π-conjugated conducting polymers [J].
Bokria, Jayesh G. ;
Kumar, Arvind ;
Seshadri, Venkataramanan ;
Tran, Arlene ;
Sotzing, Gregory A. .
ADVANCED MATERIALS, 2008, 20 (06) :1175-+
[3]   Direct C-H arylation of 3-methoxythiophene catalyzed by Pd.: Application to a more efficient synthesis of π-alkoxy-oligothiophene derivatives [J].
Borghese, A. ;
Geldhof, G. ;
Antoine, L. .
TETRAHEDRON LETTERS, 2006, 47 (52) :9249-9252
[4]   Click-functionalization of conducting poly(3,4-ethylenedioxythiophene) (PEDOT) [J].
Bu, Hang-Beom ;
Goetz, Guenther ;
Reinold, Egon ;
Vogt, Astrid ;
Schmid, Sylvia ;
Blanco, Raul ;
Segura, Jose L. ;
Baeuerle, Peter .
CHEMICAL COMMUNICATIONS, 2008, (11) :1320-1322
[5]   Conductive polymer functionalization by click chemistry [J].
Daugaard, Anders Egede ;
Hvilsted, Soren ;
Hansen, Thomas Steen ;
Larsen, Niels B. .
MACROMOLECULES, 2008, 41 (12) :4321-4327
[6]   Spray processable hybrid 3,4-propylenedioxythiophene: Phenylene electrochromic polymers [J].
Galand, Emilie M. ;
Mwaura, Jeremiah K. ;
Argun, Avni A. ;
Abboud, Khalil A. ;
McCarley, Tracy D. ;
Reynolds, John R. .
MACROMOLECULES, 2006, 39 (21) :7286-7294
[7]   Chiral ethylhexyl substituents for optically active aggregates of π-conjugated polymers [J].
Grenier, Christophe R. G. ;
George, Subi J. ;
Joncheray, Thomas J. ;
Meijer, E. W. ;
Reynolds, John R. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (35) :10694-10699
[8]   Regiosymmetric poly (dialkylphenylenedioxythiophene)s:: Electron-rich, stackable π-conjugated nanoribbons [J].
Grenier, Christophe R. G. ;
Pisula, Wojciech ;
Joncheray, Thomas J. ;
Muellen, Klaus ;
Reynolds, John R. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (05) :714-717
[9]  
GROENENDAAL L, 2000, ADV MATER, V12, P481, DOI DOI 10.1002/(SICI)1521-4095(200004)12:7<LESS
[10]   Synthesis and Characterization of Regioregular Water-Soluble 3,4-Propylenedioxythiophene Derivative and Its Application in the Fabrication of High-Contrast Solid-State Electrochromic Devices [J].
Jain, Vaibhav ;
Sahoo, Rabindra ;
Mishra, Sarada P. ;
Sinha, Jasmine ;
Montazami, Reza ;
Yochum, Hank M. ;
Heflin, James R. ;
Kumar, Anil .
MACROMOLECULES, 2009, 42 (01) :135-140