Supramolecular self-assembly of a toroidal inclusion complex, [NH4][Co8(MeCO2)8(OMe)16][PF6]

被引:38
作者
Beattie, JK [1 ]
Hambley, TW [1 ]
Klepetko, JA [1 ]
Masters, AF [1 ]
Turner, P [1 ]
机构
[1] Univ Sydney, Dept Chem, Sydney, NSW 2006, Australia
关键词
D O I
10.1039/a707228g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Diamagnetic [NH4][Co-8(MeCO2)(8)(OMe)(16)][PF6], a compound with eight cobalt atoms bridged by methoxy and acetato ligands so as to form a planar ring with an ammonium ion at its centre, is isolated from the reaction between cobalt(nr) acetate and methanol in the presence of NH4PF6.
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页码:45 / 46
页数:2
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