Alternative synthesis and crystal structures of titanocene(III)-β-diketonate complexes

被引：10

作者：

Yun, SS ^{[1
]}

Suh, IH

Kim, EH

Lee, S

机构：

[1] Chungnam Natl Univ, Dept Chem, Taejon 305764, South Korea

[2] Chungnam Natl Univ, Dept Phys, Taejon 305764, South Korea

[3] Taejon Univ, Dept Chem, Taejon 300716, South Korea

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2000年 / 51卷 / 02期

关键词：

metallocene; titanocene; crystal structure; beta-diketonate complex;

D O I：

10.1080/00958970008055128

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of titanocene prepared from Cp2TiCl2 and 2n-BuLi with beta-diketones (beta-diketone = 1-phenyl-1,3-butanedione, 1,3-diphenyl-1,3-propanedione. 3-methyl-2,4-pentanedione or 3-ethyl-2,4-pentanedione) afforded the titanocene(III) beta-diketonate complex. The compounds [Ti(eta(5)-Cp)(2)(1-phenyl-1,3-butanedionate)] and [Ti(eta(5)-Cp)(2)(1,3-diphenyl-1,3-propanedionate)] have been characterized by X-ray crystallography.

引用

页码：219 / 223

页数：5

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