Synthesis and Electrochemical Performances of MnV2O6/rGO Nanocomposite as New Anode Material for Lithium-Ion Battery Application

被引：8

作者：

Zheng, Hao ^{[1
]}

Li, Lin ^{[1
]}

Peng, Shu-Ting ^{[1
]}

Li, Mo-Xi ^{[1
]}

Yang, Li-Hong ^{[1
]}

Feng, Chuan-Qi ^{[2
]}

Yang, Shui-Jin ^{[3
]}

机构：

[1] Anshun Univ, Key Lab Funct Mat & Chem Performance & Resource, Guizhou Educ Dept, Anshun 561000, Peoples R China

[2] Hubei Univ, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Wuhan 430062, Peoples R China

[3] Hubei Normal Univ, Hubei Key Lab Pollutant Anal & Reuse Technol, Huangshi 435002, Hubei, Peoples R China

来源：

SCIENCE OF ADVANCED MATERIALS | 2021年 / 13卷 / 04期

基金：

中国国家自然科学基金;

关键词：

Manganese Vanadate; Graphene Nanosheets; Nanocomposites Materials; Lithium Ion Battery; Electrochemical Properties; GRAPHENE OXIDE; NANOSHEETS; NANOBELTS; STORAGE;

D O I：

10.1166/sam.2021.3927

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Base on high theoretical capacity and synergistic effect of metal ions of transition metal vanadate composite, the MnV2O6/graphene (MnV2O6/rGO) nanocomposite was successfully synthesized through a hydrothermal method. The MnV2O6 nanoparticles were uniformly distributed and deposited on graphene networks. Benefited from the outstanding properties of the graphene nanosheets, the electrode conductivity was improved and the volume expansion was reduced. As an anode, the MnV2O6/graphene (MnV2O6/rGO) nanocomposite exhibited excellent lithium storage properties. An initial discharge capacity was 1350 mAh g(-1), which increased to 1381 mAh g(-1) after 100 cycles at 200 mA g(-1), and showed a satisfactory reversible capacity of 640 mAh g(-1) after 400 cycles at 5000 mA g(-1).

引用

页码：642 / 649

页数：8

共 37 条

[1] Electrical Energy Storage for the Grid: A Battery of Choices [J].

Dunn, Bruce ;

Kamath, Haresh ;

Tarascon, Jean-Marie .

SCIENCE, 2011, 334 (6058) :928-935

[2] Challenges in the development of advanced Li-ion batteries: a review [J].

Etacheri, Vinodkumar ;

Marom, Rotem ;

Elazari, Ran ;

Salitra, Gregory ;

Aurbach, Doron .

ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (09) :3243-3262

[3] Pseudocapacitive sodium storage of Fe1-xS@N-doped carbon for low-temperature operation [J].

Fan, Honghong ;

Qin, Bowen ;

Wang, Zhiwei ;

Li, Huanhuan ;

Guo, Jinzhi ;

Wu, Xinglong ;

Zhang, Jingping .

SCIENCE CHINA-MATERIALS, 2020, 63 (04) :505-515

[4]

Gan LH, 2014, J MATER CHEM A, V2, P2461, DOI [10.1039/c3ta14242, 10.1039/c3ta14242f]

[5] Novel spherical cobalt/nickel mixed-vanadates as high-capacity anodes in lithium ion batteries [J].

Gong, Feng ;

Xia, Dawei ;

Zhou, Qiang ;

Liao, Jiaxuan ;

Wu, Mengqiang .

JOURNAL OF ALLOYS AND COMPOUNDS, 2018, 766 :442-449

[6] Electrosprayed porous Fe3O4/carbon microspheres as anode materials for high-performance lithium-ion batteries [J].

Han, Wenjie ;

Qin, Xianying ;

Wu, Junxiong ;

Li, Qing ;

Liu, Ming ;

Xia, Yue ;

Du, Hongda ;

Li, Baohua ;

Kang, Feiyu .

NANO RESEARCH, 2018, 11 (02) :892-904

[7] Cation-exchange synthesis of manganese vanadate nanosheets and its application in lithium-ion battery [J].

Hua, Kang ;

Li, Xiujuan ;

Fu, Zewei ;

Fang, Dong ;

Bao, Rui ;

Yi, Jianhong ;

Luo, Zhiping .

JOURNAL OF SOLID STATE CHEMISTRY, 2019, 273 :287-294

[8] Crystalline MnV2O6 nanobelts: Synthesis and electrochemical properties [J].

Huang, Wenda ;

Gao, Shaokang ;

Ding, Xiaokun ;

Jiang, Lilong ;

Wei, Mingdeng .

JOURNAL OF ALLOYS AND COMPOUNDS, 2010, 495 (01) :185-188

[9] Synthesis of MnV2O6 under autogenous hydrothermal conditions and its anodic performance [J].

Inagaki, M ;

Morishita, T ;

Hirano, M ;

Gupta, V ;

Nakajima, T .

SOLID STATE IONICS, 2003, 156 (03) :275-282

[10] Porous Fe2O3 Nanoframeworks Encapsulated within Three-Dimensional Graphene as High-Performance Flexible Anode for Lithium-Ion Battery [J].

Jiang, Tiancai ;

Bu, Fanxing ;

Feng, Xiaoxiang ;

Shakir, Imran ;

Hao, Guolin ;

Xu, Yuxi .

ACS NANO, 2017, 11 (05) :5140-5147

← 1 2 3 4 →