Influence of hydrogen bubbles adhering to the exposed surface on the corrosion rate of magnesium alloys AZ31 and AZ61 in sodium chloride solution

被引:11
作者
Feliu, S., Jr. [1 ]
Garcia-Galvan, F. R. [1 ]
Llorente, I. [1 ]
Diaz, L. [2 ]
Simancas, J. [1 ]
机构
[1] CSIC, Ctr Nacl Invest, Avda Gregorio del Amo 8, Madrid 28040, Spain
[2] Univ Simon Bolivar, Dept Ciencias Mat, Caracas 1080A, Venezuela
来源
MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION | 2017年 / 68卷 / 06期
关键词
EIS; magnesium alloys; passivity; weight loss; XPS; GAS-EVOLVING ELECTRODES; ELECTROCHEMICAL IMPEDANCE; ATMOSPHERIC CORROSION; NACL SOLUTION; MASS-LOSS; MG-ALLOY; RESISTANCE; BEHAVIOR; FILMS; TEMPERATURE;
D O I
10.1002/maco.201609233
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The influence of the presence of hydrogen bubbles adhered to the corroding specimen surface on the EIS estimations of corrosion rate of magnesium alloys is considered. The EIS corrosion rates for AZ31 specimens exposing a small area were four times higher than the real values determined by gravimetric or hydrogen evolution measurements. In contrast, no significant differences in the corrosion rate have been observed in the case of the AZ61 specimens. A progressive deterioration in the protective properties of the corrosion products layer formed during the test was observed only on AZ31 specimens exposing a small area.
引用
收藏
页码:651 / 663
页数:13
相关论文
共 64 条
[1]  
[Anonymous], ZVIEW VERS 3 1C
[2]  
Ardelean H, 2001, MATER CORROS, V52, P889, DOI 10.1002/1521-4176(200112)52:12<889::AID-MACO889>3.0.CO
[3]  
2-0
[4]   Advances in Mg corrosion and research suggestions [J].
Atrens, Andrej ;
Song, Guang-Ling ;
Cao, Fuyong ;
Shi, Zhiming ;
Bowen, Patrick K. .
JOURNAL OF MAGNESIUM AND ALLOYS, 2013, 1 (03) :177-200
[5]   Electrochemical investigation of the influence of laser surface melting on the microstructure and corrosion behaviour of ZE41 magnesium alloy - An EIS based study [J].
Banerjee, P. Chakraborty ;
Raman, R. K. Singh ;
Durandet, Y. ;
McAdam, G. .
CORROSION SCIENCE, 2011, 53 (04) :1505-1514
[6]   Assessing the Corrosion of Commercially Pure Magnesium and Commercial AZ31B by Electrochemical Impedance, Mass-Loss, Hydrogen Collection, and Inductively Coupled Plasma Optical Emission Spectrometry Solution Analysis [J].
Bland, L. G. ;
King, A. D. ;
Birbilis, N. ;
Scully, J. R. .
CORROSION, 2015, 71 (02) :128-145
[7]  
Bogenaar-Schlenter B. E., 1985, J APPL ELECTROCHEM, V15, P537
[8]   Corrosion and mechanical performance of AZ91 exposed to simulated inflammatory conditions [J].
Brooks, Emily K. ;
Der, Stephanie ;
Ehrensberger, Mark T. .
MATERIALS SCIENCE & ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS, 2016, 60 :427-436
[9]   Study of the corrosion mechanism of the in situ grown Mg-Al-CO32- hydrotalcite film on AZ31 alloy [J].
Chen, Jun ;
Song, Yingwei ;
Shan, Dayong ;
Han, En-Hou .
CORROSION SCIENCE, 2012, 65 :268-277
[10]   Atmospheric corrosion of field-exposed AZ31 magnesium in a tropical marine environment [J].
Cui, Zhongyu ;
Li, Xiaogang ;
Xiao, Kui ;
Dong, Chaofang .
CORROSION SCIENCE, 2013, 76 :243-256