Self-assembled supramolecular bidentate ligands for aqueous organometallic catalysis

被引：49

作者：

Machut, Cecile ^{[1
]}

Patrigeon, Julien ^{[1
]}

Tilloy, Sebastien ^{[1
]}

Bricout, Herve ^{[1
]}

Hapiot, Frederic ^{[1
]}

Monflier, Eric ^{[1
]}

机构：

[1] Univ Artois, LPCIA, FRE CNRS 2485, Fac Sci Jean Perrin,Federat Chevreul FR CNRS 2638, F-62307 LENS, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 17期

关键词：

cyclodextrins; hydrogenation; N; P ligands; platinum; self-assembly;

D O I：

10.1002/anie.200605166

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Sugar snap P: An N,P heterobidentate supramolecular ligand was synthesized in water by mixing a monoamino-β- cyclodextrin with an appropriate phosphane. The resultant assembly was used with a platinum(II) salt in aqueous medium to catalyze the hydrogenation of an allylic alcohol (see picture). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：3040 / 3042

页数：3

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