Confinement and Time Immemorial: Prebiotic Synthesis of Nucleotides on a Porous Mineral Nanoreactor

被引：7

作者：

Rodrigues, Francisco ^{[1
,2
]}

Georgelin, Thomas ^{[3
]}

Gaban, Guillaume ^{[3
]}

Rigaud, Baptiste ^{[4
]}

Gaslain, Fabrice ^{[5
]}

Zhuang, Guanzheng ^{[1
]}

da Fonseca, Maria Gardennia ^{[6
]}

Valtchev, Valentin ^{[7
]}

Touboul, David ^{[8
]}

Jaber, Maguy ^{[1
]}

机构：

[1] Sorbonne Univ, Lab Archeol Mol & Struct, CNRS UMR 8220, 4 Pl Jussieu, F-75005 Paris, France

[2] State Univ Paraiba, Dept Chem, UEPB, BR-58429500 Campina Grande, Paraiba, Brazil

[3] CNRS, Ctr Biophys Mol, Rue Charles Sadron, F-45000 Orleans, France

[4] CNRS, Inst Mat Paris Ctr FR2482, 4 Pl Jussieu, F-75005 Paris, France

[5] PSL Res Univ, MINES ParisTech, MAT Ctr Mat, CNRS UMR 7633, BP 87, F-91003 Evry, France

[6] Univ Fed Paraiba, Dept Chem, UFPB, BR-58059900 Joao Pessoa, Paraiba, Brazil

[7] Normandy Univ, ENSICAEN, Lab Catalyse & Spectrochim, 6 Bl Marechal Juin, F-14050 Caen, France

[8] Univ Paris Saclay, CNRS, Inst Chim Subst Nat, UPR2301, F-91198 Gif Sur Yvette, France

来源：

JOURNAL OF PHYSICAL CHEMISTRY LETTERS | 2019年 / 10卷 / 15期

关键词：

MONTMORILLONITE-CATALYZED FORMATION; RNA; PHOSPHORYLATION; POLYMERIZATION; NUCLEOSIDE; ZEOLITES; RIBOSE;

D O I：

10.1021/acs.jpclett.9b01448

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report the successful one-pot synthesis of adenosine mono-, di-, and triphosphate in the confined space of a mordenite zeolite. This is also the first report of ATP synthesized onto a porous mineral surface. The results revealed a plausible prebiotic route to ribonucleotides and highlighted the contribution of microporous minerals in the origins of life.

引用

页码：4192 / 4196

页数：9

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