Novel chromogenic pyridinium derivatives of calix[4]arenes .2.

被引:19
|
作者
Bitter, I
Grun, A
Toke, L
Toth, G
Balazs, B
MohammedZiegler, I
Grofcsik, A
Kubinyi, M
机构
[1] TECH UNIV BUDAPEST,INST GEN & ANALYT CHEM,H-1521 BUDAPEST,HUNGARY
[2] HUNGARIAN ACAD SCI,TECH ANALYT RES GRP,H-1521 BUDAPEST,HUNGARY
[3] TECH UNIV BUDAPEST,DEPT PHYS CHEM,H-1521 BUDAPEST,HUNGARY
关键词
D O I
10.1016/S0040-4020(97)10121-1
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Chromoionophoric calix[4]arenes (8,9) containing dissociable OH and quaternary pyridinium indicator groups have been synthesized, Optical measurements of the target molecules performed in various solvents in the presence of weak base and alkali cations revealed Li+, Na+ and Ca2+ recognition depending on the binding sites. Solvato- and halochromism of betaines 10,11 formed in situ upon complexation were also observed. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码:16867 / 16876
页数:10
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