Nano-structured NaLa(MoO4)2 and Eu3+-doped NaLa(MoO4)2: Synthesis, characterizations, photoluminescence and superhydrophobic properties

被引:6
作者
Yang, Chengyu [1 ]
Zhang, Lahong [1 ]
Wang, Zhen [1 ]
Li, Taohai [1 ]
Li, Feng [1 ]
Cao, Wei [2 ]
机构
[1] Xiangtan Univ, Minist Educ, Key Lab Environm Friendly Chem & Applicat, Coll Chem, Xiangtan 411105, Peoples R China
[2] Univ Oulu, Res Ctr Mol Mat, POB 3000, FIN-90014 Oulu, Finland
来源
MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS | 2016年 / 207卷
基金
中国国家自然科学基金;
关键词
NaLa(MoO4)(2); Hydrothermal; Photoluminescence; Superhydrophobic; VIBRATIONAL PROPERTIES; HYDROTHERMAL SYNTHESIS; RED PHOSPHOR; NANOCRYSTALS; LUMINESCENCE; MECHANISM; CRYSTAL; LASER;
D O I
10.1016/j.mseb.2016.02.002
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this article, we reported on controlled synthesis of nano/micro-structured NaLa(MoO4)(2) and NaLa(MoO4)(2):Eu3+ via a facile surfactant-assisted hydrothermal process. It is found that the morphology and crystallization of the molybdates are affected by such growth parameters as temperature, pH value, reaction time and reactant concentrations. The formation mechanism is suggested that contains steps of fast nucleation, self-assembly in the stabilizer, hydrothermal isolation and, finally, the micrometer scaled particle appearance The Eu3+ doped molybdate is superhydrophobic and also luminescent. These properties make the doped molybdates as potential candidates for waterproof light emitting materials. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:39 / 46
页数:8
相关论文
共 36 条
[1]   Electronic structure of β-RbSm(MoO4)2 and chemical bonding in molybdates [J].
Atuchin, V. V. ;
Aleksandrovsky, A. S. ;
Chimitova, O. D. ;
Diao, Cheng-Peng ;
Gavrilova, T. A. ;
Kesler, V. G. ;
Molokeev, M. S. ;
Krylov, A. S. ;
Bazarov, B. G. ;
Bazarova, J. G. ;
Lin, Zheshuai .
DALTON TRANSACTIONS, 2015, 44 (04) :1805-1815
[2]   Electronic structure of β-RbNd(MoO4)2 by XPS and XES [J].
Atuchin, V. V. ;
Khyzhun, O. Y. ;
Chimitova, O. D. ;
Molokeev, M. S. ;
Gavrilova, T. A. ;
Bazarov, B. G. ;
Bazarova, J. G. .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2015, 77 :101-108
[3]   Synthesis and Spectroscopic Properties of Monoclinic α-Eu2(MoO4)3 [J].
Atuchin, V. V. ;
Aleksandrovsky, A. S. ;
Chimitova, O. D. ;
Gavrilova, T. A. ;
Krylov, A. S. ;
Molokeev, M. S. ;
Oreshonkov, A. S. ;
Bazarov, B. G. ;
Bazarova, J. G. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2014, 118 (28) :15404-15411
[4]   Synthesis, structural and vibrational properties of microcrystalline β-RbSm(MoO4)2 [J].
Atuchin, V. V. ;
Chimitova, O. D. ;
Adichtchev, S. V. ;
Bazarov, J. G. ;
Gavrilova, T. A. ;
Molokeev, M. S. ;
Surovtsev, N. V. ;
Bazarova, Zh. G. .
MATERIALS LETTERS, 2013, 106 :26-29
[5]   Structural and vibrational properties of microcrystalline TIM(MoO4)2 (M = Nd, Pr) molybdates [J].
Atuchin, V. V. ;
Grossman, V. G. ;
Adichtchev, S. V. ;
Surovtsev, N. V. ;
Gavrilova, T. A. ;
Bazarov, B. G. .
OPTICAL MATERIALS, 2012, 34 (05) :812-816
[6]   Synthesis, structural and vibrational properties of microcrystalline RbNd(MoO4)2 [J].
Atuchin, V. V. ;
Chimitova, O. D. ;
Gavrilova, T. A. ;
Molokeev, M. S. ;
Kim, Sung-Jin ;
Surovtsev, N. V. ;
Bazarov, B. G. .
JOURNAL OF CRYSTAL GROWTH, 2011, 318 (01) :683-686
[7]   Oleic Acid/Oleylamine Cooperative-Controlled Crystallization Mechanism for Monodisperse Tetragonal Bipyramid NaLa(MoO4)2 Nanocrystals [J].
Bu, Wenbo ;
Chen, Zhenxing ;
Chen, Feng ;
Shi, Jianlin .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (28) :12176-12185
[8]   Unusual (μ-aqua)bis(μ-carboxylate) bridge in homometallic M(II) (M = mn, co and ni) two-dimensional compounds based on the 1,2,3,4-butanetetracarboxylic acid:: Synthesis, structure, and magnetic properties [J].
Canadillas-Delgado, Laura ;
Fabelo, Oscar ;
Pasan, Jorge ;
Delgado, Fernando S. ;
Lloret, Francesc ;
Julve, Miguel ;
Ruiz-Perez, Catalina .
INORGANIC CHEMISTRY, 2007, 46 (18) :7458-7465
[9]   The formation and structural parameters of new double molybdates RbLn(MoO4)2 (Ln = Pr, Nd, Sm, Eu) [J].
Chimitova, Olga D. ;
Atuchin, Victor V. ;
Bazarov, Bair G. ;
Molokeev, Maxim S. ;
Bazarova, Zhibzema G. .
METAMATERIALS VIII, 2013, 8771
[10]   Highly uniform NaLa(MoO4)2:Ln3+ (Ln = Eu, Dy) microspheres: template-free hydrothermal synthesis, growing mechanism, and luminescent properties [J].
Fu, Zuoling ;
Xia, Wanwan ;
Li, Qisong ;
Cui, Xiaoyun ;
Li, Wenhao .
CRYSTENGCOMM, 2012, 14 (14) :4618-4624