Impedance studies on mesocarbon microbeads supported Pt-Ru catalytic anode

被引:49
|
作者
Liu, YC [1 ]
Qiu, XP [1 ]
Zhu, WT [1 ]
Wu, GS [1 ]
机构
[1] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China
关键词
direct methanol fuel cell; impedance spectroscopy; methanol oxidation;
D O I
10.1016/S0378-7753(02)00527-X
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The impedance behaviors of direct methanol fuel cell anode using mesocarbon microbeads supported Pt-Ru catalysts were studied. A loop reflecting an inductive behavior appears at the low-frequency end only when the anode is at higher overpotential. The Nafion content in the catalyst, the MEA hot press condition and the effects of the cell temperature on the impedance behaviors of the anode electrode were also investigated. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:10 / 14
页数:5
相关论文
共 50 条
  • [1] Mesocarbon microbeads supported Pt-Ru catalysts for electrochemical oxidation of methanol
    Liu, YC
    Qiu, XP
    Huang, YQ
    Zhu, WT
    JOURNAL OF POWER SOURCES, 2002, 111 (01) : 160 - 164
  • [2] Influence of preparation process of MEA with mesocarbon microbeads supported Pt-Ru catalysts on methanol electrooxidation
    Liu, YC
    Qiu, XP
    Huang, YQ
    Zhu, WT
    Wu, GS
    JOURNAL OF APPLIED ELECTROCHEMISTRY, 2002, 32 (11) : 1279 - 1285
  • [3] Influence of preparation process of MEA with mesocarbon microbeads supported Pt-Ru catalysts on methanol electrooxidation
    Qiu, X.-P. (qiuxp@mail.tsinghua.edu.cn), 1600, Kluwer Academic Publishers (32):
  • [4] CHARACTERIZATION AND CATALYTIC STUDIES ON SUPPORTED PT-RU BIMETALLIC CLUSTERS
    MIURA, H
    GONZALEZ, RD
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1983, 185 (MAR): : 63 - PETR
  • [5] Influence of preparation process of MEA with mesocarbon microbeads supported Pt–Ru catalysts on methanol electrooxidation
    Y-C. Liu
    X-P. Qiu
    Y-Q. Huang
    W-T. Zhu
    G-S. Wu
    Journal of Applied Electrochemistry, 2002, 32 : 1279 - 1285
  • [6] CATALYTIC PROPERTIES OF PT-RU CATALYSTS
    GOMEZ, R
    CORRO, G
    DIAZ, G
    MAUBERT, A
    FIGUERAS, F
    NOUVEAU JOURNAL DE CHIMIE-NEW JOURNAL OF CHEMISTRY, 1980, 4 (11): : 677 - 681
  • [7] Electrochemical impedance analysis of methanol oxidation on carbon nanotube-supported Pt and Pt-Ru nanoparticles
    Ma, Bo
    Bai, Jincheng
    Dong, Lifeng
    JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2013, 17 (11) : 2783 - 2788
  • [8] Electrochemical impedance analysis of methanol oxidation on carbon nanotube-supported Pt and Pt-Ru nanoparticles
    Bo Ma
    Jincheng Bai
    Lifeng Dong
    Journal of Solid State Electrochemistry, 2013, 17 : 2783 - 2788
  • [9] Ceramic supported Pt and Pt-Ru catalysts for methanol oxidation
    Tarnowski, DJ
    Pu, C
    White, J
    Wixom, MR
    Thompson, LT
    PROCEEDINGS OF THE SECOND INTERNATIONAL SYMPOSIUM ON PROTON CONDUCTING MEMBRANE FUEL CELL II, 1999, 98 (27): : 280 - 290
  • [10] BIMETALLIC PT-RU SILICA SUPPORTED CATALYSTS - PREPARATION IMPLICATIONS ON STRUCTURE AND CATALYTIC ACTIVITY
    DELANGEL, G
    BERTIN, V
    BOSCH, P
    GOMEZ, R
    GONZALEZ, RD
    NEW JOURNAL OF CHEMISTRY, 1991, 15 (8-9) : 643 - 647