Effect of mixing process on the luminescent properties of SrAl2O4:Eu2+, Dy3+ long afterglow phosphors

被引:38
作者
Lue Xiao [1 ]
Sun Meng [2 ]
Zhang Junying [1 ]
Wang Tianmin [1 ]
机构
[1] Beihang Univ, Sch Phys & Nucl Energy Engn, Beijing 100191, Peoples R China
[2] Zhengzhou Univ Light Ind, Dept Technol & Phys, Zhengzhou 450002, Peoples R China
关键词
long afterglow; phosphor; SrAl2O4; trap level; decay; rare earths; PERSISTENT LUMINESCENCE; EU2+;
D O I
10.1016/S1002-0721(09)60069-7
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
A new mixing method was developed for solid-state reaction synthesis of SrAl2O4:Eu2+, Dy3+ long afterglow phosphors. The morphology and crystal structure of the phosphors were analyzed with scanning electron microscope (SEM) and X-ray diffractometer (XRD). The excitation and emission spectra of the long afterglow phosphors were measured, and the main emission band was around 514 nm. The decay time of the product was measured and compared with the phosphors prepared using dry-mixing method and wet-mixing method. It was found that the aggregates and impurities in the phosphors prepared using dry-mixing method and wet-mixing method impaired the luminescent properties. The phosphors synthesized using the new mixing method had high initial brightness and slow decay speed. This method is considered of great potential applications in industry.
引用
收藏
页码:150 / 152
页数:3
相关论文
共 11 条
[1]   Persistent luminescence of Eu2+ doped alkaline earth aluminates, MAl2O4:Eu2+ [J].
Hölsä, J ;
Jungner, H ;
Lastusaari, M ;
Niittykoski, J .
JOURNAL OF ALLOYS AND COMPOUNDS, 2001, 323 :326-330
[2]   Crystal growth and characterization of Eu2+, Dy3+:SrAl2O4 and Eu2+, Nd3+:CaAl2O4 by the LHPG method [J].
Jia, WY ;
Yuan, HB ;
Lu, LZ ;
Liu, HM ;
Yen, WM .
JOURNAL OF CRYSTAL GROWTH, 1999, 200 (1-2) :179-184
[3]   The characterization and mechanism of long afterglow in alkaline earth aluminates phosphors co-doped by Eu2O3 and Dy2O3 [J].
Lin, YH ;
Zhang, ZT ;
Tang, ZL ;
Zhang, JY ;
Zheng, ZS ;
Lu, X .
MATERIALS CHEMISTRY AND PHYSICS, 2001, 70 (02) :156-159
[4]   Preparation of the ultrafine SrAl2O4:Eu,Dy needle-like phosphor and its optical properties [J].
Lin, YH ;
Zhang, ZT ;
Zhang, F ;
Tang, ZL ;
Chen, QM .
MATERIALS CHEMISTRY AND PHYSICS, 2000, 65 (01) :103-106
[5]   New long phosphorescent phosphor with high brightness, SrAl2O4:Eu2+,Dy3+ [J].
Matsuzawa, T ;
Aoki, Y ;
Takeuchi, N ;
Murayama, Y .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (08) :2670-2673
[6]  
MATSUZAWA T, 1997, J ELECTROCHEM SOC, V144, pL243
[7]   Temperature dependence of persistent luminescence in β-irradiated SrAl2O4:Eu2+, Dy3+ phosphor [J].
Melendrez, R. ;
Arellano-Tanori, O. ;
Pedroza-Montero, M. ;
Yen, W. M. ;
Barboza-Flores, M. .
JOURNAL OF LUMINESCENCE, 2009, 129 (07) :679-685
[8]  
Murayama Y., 1995, US Patent, Patent No. [5, 424, 006, 5424006]
[9]   Role of B2O3 on the phase stability and long phosphorescence of SrAl2O4:Eu, Dy [J].
Nag, A ;
Kutty, TRN .
JOURNAL OF ALLOYS AND COMPOUNDS, 2003, 354 (1-2) :221-231
[10]  
RONDA CR, 1997, J LUMIN, V49, P72