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Noble Metal Nanoparticles Stabilized by Cyclodextrins: A Pertinent Partnership for Catalytic Applications
被引:15
作者:
Denicourt-Nowicki, A.
[1
,2
]
Roucoux, A.
[1
,2
]
机构:
[1] Ecole Natl Super Chim Rennes, CNRS, UMR 6226, F-35708 Rennes 7, France
[2] Univ Europeenne Bretagne, Rennes, France
关键词:
Nanoparticles;
Noble metal;
Cyclodextrins;
Catalysis;
Water;
CAPPED PALLADIUM NANOPARTICLES;
GAS-PHASE HYDROGENATION;
O-XYLENE HYDROGENATION;
BETA-CYCLODEXTRIN;
GOLD NANOPARTICLES;
METHYLATED CYCLODEXTRINS;
RUTHENIUM NANOPARTICLES;
ARENE HYDROGENATION;
SUPRAMOLECULAR SHUTTLE;
ALPHA-CYCLODEXTRIN;
D O I:
10.2174/138527210791616911
中图分类号:
O62 [有机化学];
学科分类号:
070303 ;
081704 ;
摘要:
For economic and ecological purposes, the design of stable and reusable noble metal nanoparticles in water has become a concern over the past few years. Among the various water-soluble protective agents, cyclodextrins proved to be attractive candidates to efficiently stabilize catalytically active nanospecies in aqueous media and also to improve the mass transfer in aqueous-organic two-phase systems. Various catalytic reactions such as arenes hydrogenations, olefins reduction or cross-coupling reactions were successfully achieved with good yields and selectivities according to the relevant choice of the cyclodextrins (cavity or functionalization).
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页码:1266 / 1283
页数:18
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