Photoactivation of triosmium dodecacarbonyl at 400 nm probed with time-resolved X-ray liquidography

被引：4

作者：

Ki, Hosung ^{[1
,2
,3
]}

Kim, Tae Wu ^{[4
]}

Moon, Jiwon ^{[5
]}

Kim, Jungmin ^{[1
,2
,3
]}

Lee, Yunbeom ^{[1
,2
,3
]}

Heo, Jun ^{[1
,2
,3
]}

Kim, Kyung Hwan ^{[6
]}

Kong, Qingyu ^{[7
]}

Khakhulin, Dmitry ^{[8
]}

Newby, Gemma ^{[9
]}

Kim, Joonghan ^{[5
]}

Kim, Jeongho ^{[10
]}

Wulff, Michael ^{[9
]}

Ihee, Hyotcherl ^{[1
,2
,3
]}

机构：

[1] Inst Basic Sci IBS, Ctr Adv React Dynam, Daejeon 34141, South Korea

[2] Korea Adv Inst Sci & Technol KAIST, Dept Chem, Daejeon 34141, South Korea

[3] Korea Adv Inst Sci & Technol KAIST, KI BioCentury, Daejeon 34141, South Korea

[4] Mokpo Natl Univ, Dept Chem, Muan Gun 58554, Jeollanam Do, South Korea

[5] Catholic Univ Korea, Dept Chem, Bucheon 14662, South Korea

[6] Pohang Univ Sci & Technol POSTECH, Dept Chem, Pohang 37673, South Korea

[7] Synchrotron Soleil, BP 48, F-91192 Gif Sur Yvette, France

[8] European XFEL, Halzkoppel 4, D-22869 Schenefeld, Germany

[9] European Synchrotron Radiat Facil, BP 220, F-38043 Grenoble, France

[10] Inha Univ, Dept Chem, Incheon 22212, South Korea

来源：

CHEMICAL COMMUNICATIONS | 2022年 / 58卷 / 53期

关键词：

SOLUTION SCATTERING REVEALS; M-3(CO)(12) M; OS3(CO)12; CLUSTERS; DYNAMICS; PHOTOCHEMISTRY; PHOTOREACTIONS; RU-3(CO)(12); REACTIVITY; PHOTOLYSIS;

D O I：

10.1039/d2cc02438a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The photoactivation mechanism of Os-3(CO)(12) at 400 nm is examined with time-resolved X-ray liquidography. The data reveal two pathways: the vibrational relaxation following an internal conversion to the electronic ground state and the ligand dissociation to form Os-3(CO)(11) with a ligand vacancy at the axial position.

引用

页码：7380 / 7383

页数：4

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