Photoactivation of triosmium dodecacarbonyl at 400 nm probed with time-resolved X-ray liquidography

被引：4
作者：
Ki, Hosung [1 ,2 ,3 ]
Kim, Tae Wu [4 ]
Moon, Jiwon [5 ]
Kim, Jungmin [1 ,2 ,3 ]
Lee, Yunbeom [1 ,2 ,3 ]
Heo, Jun [1 ,2 ,3 ]
Kim, Kyung Hwan [6 ]
Kong, Qingyu [7 ]
Khakhulin, Dmitry [8 ]
Newby, Gemma [9 ]
Kim, Joonghan [5 ]
Kim, Jeongho [10 ]
Wulff, Michael [9 ]
Ihee, Hyotcherl [1 ,2 ,3 ]
机构：
[1] Inst Basic Sci IBS, Ctr Adv React Dynam, Daejeon 34141, South Korea
[2] Korea Adv Inst Sci & Technol KAIST, Dept Chem, Daejeon 34141, South Korea
[3] Korea Adv Inst Sci & Technol KAIST, KI BioCentury, Daejeon 34141, South Korea
[4] Mokpo Natl Univ, Dept Chem, Muan Gun 58554, Jeollanam Do, South Korea
[5] Catholic Univ Korea, Dept Chem, Bucheon 14662, South Korea
[6] Pohang Univ Sci & Technol POSTECH, Dept Chem, Pohang 37673, South Korea
[7] Synchrotron Soleil, BP 48, F-91192 Gif Sur Yvette, France
[8] European XFEL, Halzkoppel 4, D-22869 Schenefeld, Germany
[9] European Synchrotron Radiat Facil, BP 220, F-38043 Grenoble, France
[10] Inha Univ, Dept Chem, Incheon 22212, South Korea
来源：
CHEMICAL COMMUNICATIONS | 2022年 / 58卷 / 53期
关键词：
SOLUTION SCATTERING REVEALS; M-3(CO)(12) M; OS3(CO)12; CLUSTERS; DYNAMICS; PHOTOCHEMISTRY; PHOTOREACTIONS; RU-3(CO)(12); REACTIVITY; PHOTOLYSIS;
D O I：
10.1039/d2cc02438a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The photoactivation mechanism of Os-3(CO)(12) at 400 nm is examined with time-resolved X-ray liquidography. The data reveal two pathways: the vibrational relaxation following an internal conversion to the electronic ground state and the ligand dissociation to form Os-3(CO)(11) with a ligand vacancy at the axial position.
引用
收藏
页码：7380 / 7383
页数：4
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