Oxidative Preparation of Aromatic Orthocarboxylates from Aldehydes

被引：2

作者：

Tanabe, Hiroyuki ^{[2
]}

He, Xinyao ^{[1
]}

Kothandaraman, Prasath ^{[1
]}

Yamane, Motoki ^{[1
]}

机构：

[1] Nanyang Technol Univ, Sch Math & Phys Sci, Div Chem & Biol Chem, Singapore 637371, Singapore

[2] Univ Tsukuba, Grad Sch Pure & Appl Sci, Dept Chem, Tsukuba, Ibaraki 3058571, Japan

来源：

SYNLETT | 2010年 / 08期

关键词：

orthoester; oxidation; acetal; aldehyde; one-pot reaction; 3,4-DIMETHOXYBENZYL PROTECTING GROUPS; ORTHO-ESTERS; SYNTHETIC APPLICATIONS; ASYMMETRIC-SYNTHESIS; MPM; 4-METHOXYBENZYL; HYDROXY FUNCTIONS; REACTIVITY; ACETALS; BENZYL; ACIDS;

D O I：

10.1055/s-0029-1219793

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aromatic orthocarboxylates are oxidatively synthesized in good yields from hydroxyacetals derived from the corresponding aromatic aldehydes. In situ generation of hydroxyacetal and successive oxidation by DDQ provides a one-pot preparation of aromatic orthocarboxylates from aldehydes.

引用

页码：1190 / 1192

页数：3

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