Iron-catalysed chemo- and ortho-selective C-H bond functionalization of phenols with α-aryl-α-diazoacetates

被引：21

作者：

Yu, Zhunzhun ^{[1
]}

Li, Guanghui ^{[1
]}

Zhang, Junliang ^{[2
]}

Liu, Lu ^{[1
,3
]}

机构：

[1] East China Normal Univ, Sch Chem & Mol Engn, 500 Dongchuan Rd, Shanghai 200241, Peoples R China

[2] Fudan Univ, Dept Chem, 2005 Songhu Rd, Shanghai 200438, Peoples R China

[3] East China Normal Univ, Shanghai Engn Res Ctr Mol Therapeut & New Drug De, Shanghai 200062, Peoples R China

来源：

ORGANIC CHEMISTRY FRONTIERS | 2021年 / 8卷 / 14期

基金：

中国国家自然科学基金;

关键词：

ASYMMETRIC CYCLOPROPANATION; INTRAMOLECULAR CYCLOPROPANATION; C(SP(2))-H FUNCTIONALIZATION; INSERTION REACTIONS; METAL-COMPLEXES; DIAZO REAGENTS; GOLD; COBALT; PORPHYRIN; COPPER;

D O I：

10.1039/d1qo00276g

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Herein we present a novel iron-catalyzed chemo- and regio-selective ortho C-H bond functionalization of phenols and naphthols with diazo compounds. In this transformation, an iron porphyrin exhibits specific catalytic activity, and is quite different from the commonly used precious metal catalysts.

引用

页码：3770 / 3775

页数：6

共 88 条

[1] First-Row Transition Metal (De)Hydrogenation Catalysis Based On Functional Pincer Ligands
Alig, Lukas
Fritz, Maximilian
Schneider, Sven
[J]. CHEMICAL REVIEWS, 2019, 119 (04) : 2681 - 2751
[2] [Anonymous], 1998, Modern Catalytic Methods for Organic Synthesis with Diazo Compounds
[3] SELECTIVE INTERMOLECULAR CARBON-HYDROGEN BOND ACTIVATION BY SYNTHETIC METAL-COMPLEXES IN HOMOGENEOUS SOLUTION
ARNDTSEN, BA
BERGMAN, RG
MOBLEY, TA
PETERSON, TH
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1995, 28 (03) : 154 - 162
[4] Arockiam PB, 2012, CHEM REV, V112, P5879, DOI [10.1021/cr300153J, 10.1021/cr300153j]
[5] Iron Catalysis in Organic Synthesis
Bauer, Ingmar
Knoelker, Hans-Joachim
[J]. CHEMICAL REVIEWS, 2015, 115 (09) : 3170 - 3387
[6] Iron porphyrin catalyzed N-H insertion reactions with ethyl diazoacetate
Baumann, Lynnette K.
Mbuvi, Harun M.
Du, Guodong
Woo, L. Keith
[J]. ORGANOMETALLICS, 2007, 26 (16) : 3995 - 4002
[7] Iron-catalyzed reactions in organic synthesis
Bolm, C
Legros, J
Le Paih, J
Zani, L
[J]. CHEMICAL REVIEWS, 2004, 104 (12) : 6217 - 6254
[8] BINOL: A versatile chiral reagent
Brunel, JM
[J]. CHEMICAL REVIEWS, 2005, 105 (03) : 857 - 897
[9] PORPHYRIN SPONGES - CONSERVATION OF HOST STRUCTURE IN OVER 200 PORPHYRIN-BASED LATTICE CLATHRATES
BYRN, MP
CURTIS, CJ
HSIOU, Y
KHAN, SI
SAWIN, PA
TENDICK, SK
TERZIS, A
STROUSE, CE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (21) : 9480 - 9497
[10] Iron-Catalyzed C?H Fuctionalization of Indoles
Cai, Yan
Zhu, Shou-Fei
Wang, Guo-Peng
Zhou, Qi-Lin
[J]. ADVANCED SYNTHESIS & CATALYSIS, 2011, 353 (16) : 2939 - 2944

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