Hydrolysis of (Me3SiCH2)PhSnCl2.: Isomerisation of the dimeric tetraorganodistannoxane [(Me3SiCH2)Ph(Cl)SnOSn(Cl)Ph(CH2SiMe3)]

被引：15

作者：

Beckmann, J

Dakternieks, D ^{[1
]}

Duthie, A

Tiekink, ERT

机构：

[1] Deakin Univ, Ctr Chiral & Mol Technol, Geelong, Vic 3217, Australia

[2] Univ Adelaide, Dept Chem, Adelaide, SA 5005, Australia

来源：

DALTON TRANSACTIONS | 2003年 / 04期

关键词：

D O I：

10.1039/b211070a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The hydrolysis of (Me3SiCH2)PhSnCl2 (1)was studied under two different reaction conditions (i) by using an excess of aqueous NaOH in toluene at reflux temperature and (ii) by using small amounts of NEt3 and water in CH2Cl2 at room temperature. For (i) the products (Me3SiCH2)Ph2SnOSnPh2(CH2SiMe3) (2) and [(Me3SiCH2Sn)(12)O-14(OH)(6)](OH)(2) (3) were isolated indicating that a phenyl group migration took place. For (ii) the dimeric tetraorganodistannoxane [(Me3SiCH2)Ph(Cl)SnOSn(Cl)Ph(CH2SiMe3)](2) (4) was obtained. In solution, 4 exists as an equilibrium mixture of all five possible isomers 4a-4e; in the solid state two of these isomers 4d and 4e co-crystallized in the same crystal modi cation. The observation of interconvertible isomers of 4 was attributed to the kinetic lability of the ladder-like Sn4O2Cl4 structural motif. Compounds 1 and 4 were investigated by X-ray crystallography.

引用

页码：755 / 759

页数：5

共 34 条

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