Synthesis of magnetically recyclable MnFe2O4@SiO2@Ag nanocatalyst: Its high catalytic performances for azo dyes and nitro compounds reduction

被引:111
作者
Kurtan, U. [1 ]
Amir, Md. [1 ]
Yildiz, A. [2 ]
Baykal, A. [1 ]
机构
[1] Fatih Univ, Dept Chem, TR-34500 Istanbul, Turkey
[2] Namik Kemal Univ, Dept Text Engn, TR-59860 Corlu Tekirdag, Turkey
关键词
Heterogenous catalyst; Magnetic recyclable nanocatalyts; Hydrogenation; Azo dye; Aromatic nitro compounds; SILVER NANOPARTICLES; FACILE SYNTHESIS; NANOCOMPOSITE; HYDROGENATION; DEGRADATION; COMPOSITES; ADSORPTION; REMOVAL; SOLVENT;
D O I
10.1016/j.apsusc.2016.02.120
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this study, magnetically recycable MnFe2O4@SiO2@Ag nanocatalyst (MnFe2O4@SiO2@Ag MRCs) has been synthesized through co-precipition and chemical reduction method. XRD analysis confirmed the synthesis of single phase nanoproduct with crystallite size of 10 nm. VSM measurements showed the superparamagnetic property of the product. Catalytic studies showed that MnFe2O4@SiO2@Ag MRC could catalyze the reduction of the various azo compounds like methyl orange (MO), methylene blue (MB), eosin Y (EY), and rhodamine B (RhB) and also aromatic nitro compounds such as 4-nitrophenol (4-NP), 4-nitroaniline (4-NA) and 2-nitroaniline (2-NA). Moreover, the magnetic nanocatalyst showed an excellent reusability properties that remained unchanged after several cycles. Therefore, MnFe2O4@SiO2@Ag is the potential candidate for the application of organic pollutants for wastewater treatment. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:16 / 25
页数:10
相关论文
共 48 条
[1]  
Aljamali N.M., 2015, BIOCH ANAL BIOCH, V4
[2]   Rapid color degradation of organic dyes by Fe3O4@His@Ag recyclable magnetic nanocatalyst [J].
Amir, Md ;
Kurtan, U. ;
Baykal, A. .
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2015, 27 :347-353
[3]  
[Anonymous], 2012, MATER CHEM PHYS, DOI [DOI 10.1016/J.MATCHEMPHYS.2012.03.035, DOI 10.1016/J.MATCHEM-PHYS.2012.03.035]
[4]   Facile Synthesis of Silver Nanoparticles Stabilized by Cationic Polynorbornenes and Their Catalytic Activity in 4-Nitrophenol Reduction [J].
Baruah, Bharat ;
Gabriel, Gregory J. ;
Akbashev, Michelle J. ;
Booher, Matthew E. .
LANGMUIR, 2013, 29 (13) :4225-4234
[5]   Analysis of the reactions used for the preparation of drug candidate molecules [J].
Carey, John S. ;
Laffan, David ;
Thomson, Colin ;
Williams, Mike T. .
ORGANIC & BIOMOLECULAR CHEMISTRY, 2006, 4 (12) :2337-2347
[6]  
CHEN Y, 2005, CHEM COMMUN, V529, P8
[7]   One-pot synthesis of ordered mesoporous silver nanoparticle/carbon composites for catalytic reduction of 4-nitrophenol [J].
Chi, Yue ;
Tu, Jinchun ;
Wang, Minggang ;
Li, Xiaotian ;
Zhao, Zhankui .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2014, 423 :54-59
[8]   Synthesis of Fe3O4@SiO2-Ag magnetic nanocomposite based on small-sized and highly dispersed silver nanoparticles for catalytic reduction of 4-nitrophenol [J].
Chi, Yue ;
Yuan, Qing ;
Li, Yanjuan ;
Tu, Jinchun ;
Zhao, Liang ;
Li, Nan ;
Li, Xiaotian .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2012, 383 :96-102
[9]   Non-conventional low-cost adsorbents for dye removal: A review [J].
Crini, G .
BIORESOURCE TECHNOLOGY, 2006, 97 (09) :1061-1085
[10]   Studies on adsorption of dyes on beta-cyclodextrin polymer [J].
Crini, G .
BIORESOURCE TECHNOLOGY, 2003, 90 (02) :193-198